Preparation of Polymer Blends between Poly (L-lactic acid), Poly (butylene succinate-co-adipate) and Poly (butylene adipate-co-terephthalate) for Blow Film Industrial Application

被引:31
作者
Pivsa-Art, Weraporn [1 ]
Pavasupree, Sorapong [1 ]
O-Charoen, Narongchai [1 ]
Insuan, Ubon [1 ]
Jailak, Puritud [1 ]
Pivsa-Art, Sommai [1 ]
机构
[1] Rajamangala Univ Technol Thanyaburi, Fac Engn, Dept Chem & Mat Engn, Thanyaburi 12110, Pathumthani, Thailand
来源
9TH ECO-ENERGY AND MATERIALS SCIENCE AND ENGINEERING SYMPOSIUM | 2011年 / 9卷
关键词
Blown film extrusion; Poly(lactic acid) (PLA; Poly(butylene succinate-co-adipate) (PBSA); Poly) butylene adipate terephthalate((PBAT); Polymer blend; ADIPATE-CO-TEREPHTHALATE) BLENDS; ALIPHATIC POLYESTERS; POLY(LACTIC ACID); BEHAVIOR; PLA;
D O I
10.1016/j.egypro.2011.09.068
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The preparation of polymer blends of poly (lactic acid) (PLA), Poly(butylene-succinate-co-adipate)(PBSA) and poly) butylene adipate-co-terephthalate((PBAT) were studied with the objectives to apply to blown film extrusion method. The blends were prepared using twin-screw extruder. The ratio of PLA and PBSA was fixed at 80/20 and the PBAT content was investigated with 0, 10, 20, 30, 40 and 50 wt%. The speed of screw was 80 rpm with the die temperatures of 220, 200, and 180 C. It was found that the melt flow index) MFI(and tensile strength of blends decreased with increasing amount of PBAT, whereas the percentage strain showed contrastive results. The maximum tensile strength and impact strength were reached with the blend of equal amount 20 wt% of PBAT. Then, the correspondent condition was used in the blown film extrusion process. The morphology investigation using scanning electronic microscopy) SEM(of PLA/PBSA/PBAT blends showed an excellent compatibility between the three polymers. (C) 2011 Published by Elsevier Ltd. Selection and/or peer-review under responsibility of CEO of Sustainable Energy System, Rajamangala University of Technology Thanyaburi (RMUTT).
引用
收藏
页数:8
相关论文
共 14 条
[1]  
Bhatia A, 2007, KOREA-AUST RHEOL J, V19, P125
[2]   Rheological properties of amorphous and semicrystalline polylactic acid polymers [J].
Fang, Q ;
Hanna, MA .
INDUSTRIAL CROPS AND PRODUCTS, 1999, 10 (01) :47-53
[3]   Processability and properties of aliphatic polyesters, 'BIONOLLE', synthesized by polycondensation reaction [J].
Fujimaki, T .
POLYMER DEGRADATION AND STABILITY, 1998, 59 (1-3) :209-214
[4]   Melt rheology of polylactide/poly(butylene adipate-co-terephthalate) blends [J].
Gu, Shu-Ying ;
Zhang, Ke ;
Ren, Jie ;
Zhan, Hui .
CARBOHYDRATE POLYMERS, 2008, 74 (01) :79-85
[5]  
Huang S. J, 1985, ENCY POLYM SCI ENG 2
[6]   Study of biodegradable polyactide/poly(butylene adipate-co-terephthalate) blends [J].
Jiang, L ;
Wolcott, MP ;
Zhang, JW .
BIOMACROMOLECULES, 2006, 7 (01) :199-207
[7]   Poly(lactic acid):: plasticization and properties of biodegradable multiphase systems [J].
Martin, O ;
Avérous, L .
POLYMER, 2001, 42 (14) :6209-6219
[8]   Crystallization behaviour of poly(L-lactide) [J].
Miyata, T ;
Masuko, T .
POLYMER, 1998, 39 (22) :5515-5521
[9]  
Ogata N, 1997, J POLYM SCI POL PHYS, V35, P389, DOI 10.1002/(SICI)1099-0488(19970130)35:2<389::AID-POLB14>3.0.CO
[10]  
2-E