Synthesis and characterization of cobalt(II) complexes with two twelve-membered tetraaza macrocyclic ligands

被引：12

作者：

Chandra, S ^{[1
]}

Sharma, SD ^{[1
]}

Kumar, U ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Zakir Husain Coll, New Delhi 110002, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2004年 / 34卷 / 01期

关键词：

cobalt(II) complexes; DAED; BDAP; synthesis; characterization;

D O I：

10.1081/SIM-120027318

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cobalt(H) complexes of the general composition CoLX2 {where X = Cl, 1/2 SO4, NO3, and SCN; L = 2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene [N-4] (DAED) or 2,3,8,9-tetraphenyl-5,11-dimethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene[N-4] (BDAP)} have been prepared. On the basis of electronic and EPR spectral studies, the chloro, nitrato and thiocyanato complexes were found to have six-coordinate, octahedral geometry and the sulfato complexes were found to have five-coordinate, trigonal-bipyramidal geometry.

引用

页码：79 / 91

页数：13

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