Carbon-metal oxide nanocomposites as lithium-sulfur battery cathodes

被引：31

作者：

Zhu, Sheng ^{[1
]}

Li, Yan ^{[1
]}

机构：

[1] Peking Univ, Key Lab Phys & Chem Nanodevices, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Beijing, Peoples R China

来源：

FUNCTIONAL MATERIALS LETTERS | 2018年 / 11卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Carbon; metal oxides; rechargeable; lithium-sulfur batteries; cathodes; HIGH-PERFORMANCE CATHODE; REDUCED-GRAPHENE-OXIDE; NITROGEN-DOPED CARBON; POROUS CARBON; SOLID-ELECTROLYTE; MNO2; NANOSHEETS; HOLLOW SPHERES; HOST MATERIAL; IN-SITU; NANOTUBES;

D O I：

10.1142/S1793604718300074

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In rechargeable lithium-sulfur (Li-S) batteries, the conductive carbon materials with high surface areas can greatly enhance the electrical conductivity of sulfur cathode, and metal oxides can restrain the dissolution of lithium polysulfides within the electrolyte through strong chemical bindings. The rational design of carbon-metal oxide nanocomposite cathodes has been considered as an effective solution to increase the sulfur utilization and improve cycling performance of Li-S batteries. Here, we summarize the recent progresses in the carbon-metal oxide composites for Li-S battery cathodes. Some insights are also offered on the future directions of carbon-metal oxide hybrid cathodes for high performance Li-S batteries.

引用

页数：7

共 91 条

[1] Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes [J].

Adams, Brian D. ;

Carino, Emily V. ;

Connell, Justin G. ;

Han, Kee Sung ;

Cao, Ruiguo ;

Chen, Junzheng ;

Zheng, Jianming ;

Li, Qiuyan ;

Mueller, Karl T. ;

Henderson, Wesley A. ;

Zhang, Ji-Guang .

NANO ENERGY, 2017, 40 :607-617

[2] Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries [J].

Ahn, Wook ;

Kim, Kwang-Bum ;

Jung, Kyu-Nam ;

Shin, Kyoung-Hee ;

Jin, Chang-Soo .

JOURNAL OF POWER SOURCES, 2012, 202 :394-399

[3] MnO modified carbon nanotubes as a sulfur host with enhanced performance in Li/S batteries [J].

An, Taihua ;

Deng, Dingrong ;

Lei, Ming ;

Wu, Qi-Hui ;

Tian, Zhaowu ;

Zheng, Mingsen ;

Dong, Quanfeng .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (33) :12858-12864

[4] Ultrafine TiO2 Confined in Porous-Nitrogen-Doped Carbon from Metal- Organic Frameworks for High-Performance Lithium Sulfur Batteries [J].

An, Yongling ;

Zhang, Zhen ;

Fei, Huifang ;

Xiong, Shenglin ;

Ji, Bing ;

Feng, Jinkui .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (14) :12400-12407

[5]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/NMAT3191, 10.1038/nmat3191]

[6] Hydrothermal carbon-based nanostructured hollow spheres as electrode materials for high-power lithium-sulfur batteries [J].

Brun, Nicolas ;

Sakaushi, Ken ;

Yu, Linghui ;

Giebeler, Lars ;

Eckert, Juergen ;

Titirici, Magdalena M. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (16) :6080-6087

[7] SiO2-coated sulfur particles with mildly reduced graphene oxide as a cathode material for lithium-sulfur batteries [J].

Campbell, Brennan ;

Bell, Jeffrey ;

Bay, Hamed Hosseini ;

Favors, Zachary ;

Ionescu, Robert ;

Ozkan, Cengiz S. ;

Ozkan, Mihrimah .

NANOSCALE, 2015, 7 (16) :7051-7055

[8] MnO2 nanosheets grown on the internal/external surface of N-doped hollow porous carbon nanospheres as the sulfur host of advanced lithium-sulfur batteries [J].

Chen, Manfang ;

Lu, Qun ;

Jiang, Shouxin ;

Huang, Cheng ;

Wang, Xianyou ;

Wu, Bing ;

Xiang, Kaixiong ;

Wu, Yuting .

CHEMICAL ENGINEERING JOURNAL, 2018, 335 :831-842

[9] Multi-shelled hollow carbon nanospheres for lithium-sulfur batteries with superior performances [J].

Chen, Shuangqiang ;

Huang, Xiaodan ;

Sun, Bing ;

Zhang, Jinqiang ;

Liu, Hao ;

Wang, Guoxiu .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (38) :16199-16207

[10] The gap between long lifespan Li-S coin and pouch cells: The importance of lithium metal anode protection [J].

Cheng, Xin-Bing ;

Yan, Chong ;

Huang, Jia-Qi ;

Li, Peng ;

Zhu, Lin ;

Zhao, Lida ;

Zhang, Yingying ;

Zhu, Wancheng ;

Yang, Shu-Ting ;

Zhang, Qiang .

ENERGY STORAGE MATERIALS, 2017, 6 :18-25

← 1 2 3 4 5 6 7 8 9 10 →