Enhancing the long-term stability of Ag based seals for solid oxide fuel/electrolysis applications by simple interconnect aluminization

被引：17
作者：
Si, Xiaoqing [1 ,2 ]
Cao, Jian [2 ]
Ritucci, Ilaria [1 ]
Talic, Belma [1 ]
Feng, Jicai [2 ]
Kiebach, Ragnar [1 ]
机构：
[1] Tech Univ Denmark, Dept Energy Convers & Storage, Riso Campus, DK-4000 Roskilde, Denmark
[2] Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Heilongjiang, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2019年 / 44卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Reactive air brazing; Aluminization; Ag-CuO braze; Solid oxide fuel cell; Solid oxide electrolysis cell; High temperature corrosion; FUEL-CELL; THERMAL-EXPANSION; STAINLESS-STEEL; GLASS; PERFORMANCE; YSZ; TOLERANCE; JOINTS; COPPER; STACK;
D O I：
10.1016/j.ijhydene.2018.11.071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ag-(0-8 mol%) CuO is used to successfully join aluminized ferritic stainless steel interconnect to the ceria-gadolinia (CGO) barrier layer of a solid oxide fuel/electrolysis cell by reactive air brazing at 1000 degrees C in air. The wetting of Ag-CuO on CGO is tailored by varying the CuO content. The effects of the CuO content on the joint microstructure are discussed. The long-term stability of brazed joints is evaluated by aging in oxidizing (air) and reducing (4% H-2-50% H2O-N-2) atmospheres at 800 degrees C for 250 h. An Ag-2mol% CuO braze results in the best joint stability during aging. Aluminization of the steel to create an alumina surface layer provides excellent protection of the steel both during the joining process and aging in the 2 atm. No degradation related to steel corrosion and outward diffusion of elements from the steel can be observed. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：3063 / 3074
页数：12
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