Separation of parent homopolymers from diblock copolymers by liquid chromatography under limiting conditions desorption, 1 - Principle of the method

被引:34
作者
Berek, Dusan [1 ]
机构
[1] Slovak Acad Sci, Inst Polymer, Lab Liquid Chromatog, Bratislava 84236, Slovakia
关键词
diblock copolymers; liquid chromatography under limiting conditions of enthalpic interactions; parent homopolymers; separation of polymers;
D O I
10.1002/macp.200700540
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel group of liquid chromatographic methods was developed, namely liquid chromatography under limiting conditions of enthalpic interactions (LC LC). LC LC utilizes the difference in the elution rates of the slow, pore permeating small solvent molecules and the fast traveling pore excluded macromolecules. The appropriately chosen small molecules create a barrier, which selectively promotes enthalpic interactions of one kind of polymer chains within the chromatographic system and thus blocks their fast elution. The non-interacting polymer chains elute rapidly. Two different barriers enable simultaneous separation of both parent homopolymers from a diblock copolymer.
引用
收藏
页码:695 / 706
页数:12
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