A perspective on slow-relaxing molecular magnets built from rare-earths and nitronyl-nitroxide building blocks (invited)

被引：35

作者：

Bogani, Lapo ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Phys 1, D-70550 Stuttgart, Germany

来源：

JOURNAL OF APPLIED PHYSICS | 2011年 / 109卷 / 07期

关键词：

SINGLE-CHAIN MAGNETS; ISING-MODEL; MAGNETIZATION; FAMILY; NANOMAGNETS; COMPLEXES; RADICALS; BEHAVIOR; QUBITS;

D O I：

10.1063/1.3561103

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

We offer a perspective, accessible to both chemists and physicists, of recent developments in the synthesis and characterization of molecular magnetic materials based on rare-earths and nitronyl-nitroxide radicals. We show both the rationale of the synthetic strategies and the observed behaviors. We highlight the relevance of these findings for synthetic chemists, material scientists, and physicists. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3561103]

引用

页数：6

共 55 条

[1] Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9- and [Ln(β2-SiW11O39)2]13- (LnIII = Tb, Dy, Ho, Er, Tm, and Yb) [J].

AlDamen, Murad A. ;

Cardona-Serra, Salvador ;

Clemente-Juan, Juan M. ;

Coronado, Eugenio ;

Gaita-Arino, Alejandro ;

Marti-Gastaldo, Carlos ;

Luis, Fernando ;

Montero, Oscar .

INORGANIC CHEMISTRY, 2009, 48 (08) :3467-3479

[2] MAGNETIC-ORDERING IN A MOLECULAR MATERIAL CONTAINING DYSPROSIUM(III) AND A NITRONYL NITROXIDE [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

SESSOLI, R .

ADVANCED MATERIALS, 1992, 4 (7-8) :504-505

[3] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[4] GADOLINIUM(III) COMPLEXES WITH PYRIDINE-SUBSTITUTED NITRONYL NITROXIDE RADICALS [J].

BENELLI, C ;

CANESCHI, A ;

GATTESCHI, D ;

PARDI, L .

INORGANIC CHEMISTRY, 1992, 31 (05) :741-746

[5] [TmIII(hfac)3(NITPhOPh)]∞:: A new member of a lanthanide-based single chain magnets family [J].

Bernot, K. ;

Bogani, L. ;

Sessoli, R. ;

Gatteschi, D. .

INORGANICA CHIMICA ACTA, 2007, 360 (13) :3807-3812

[6]

BERNOT K, 2008, THESIS U FLORENCE FL

[7] A family of rare-earth-based single chain magnets: Playing with anisotropy [J].

Bernot, Kevin ;

Bogani, Lapo ;

Caneschi, Andrea ;

Gatteschi, Dante ;

Sessoli, Roberta .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (24) :7947-7956

[8] Magnetic Anisotropy of Dysprosium(III) in a Low-Symmetry Environment: A Theoretical and Experimental Investigation [J].

Bernot, Kevin ;

Luzon, Javier ;

Bogani, Lapo ;

Etienne, Mael ;

Sangregorio, Claudio ;

Shanmugam, Muralidharan ;

Caneschi, Andrea ;

Sessoli, Roberta ;

Gatteschi, Dante .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (15) :5573-5579

[9] Rare-earth solid-state qubits [J].

Bertaina, S. ;

Gambarelli, S. ;

Tkachuk, A. ;

Kurkin, I. N. ;

Malkin, B. ;

Stepanov, A. ;

Barbara, B. .

NATURE NANOTECHNOLOGY, 2007, 2 (01) :39-42

[10] Finite-size effects on the static properties of a single-chain magnet [J].

Bogani, L ;

Sessoli, R ;

Pini, MG ;

Rettori, A ;

Novak, MA ;

Rosa, P ;

Massi, M ;

Fedi, ME ;

Giuntini, L ;

Caneschi, A ;

Gatteschi, D .

PHYSICAL REVIEW B, 2005, 72 (06)

← 1 2 3 4 5 6 →