[μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN2)propan-2-olato-κ2O:O]bis[(ethanol-κO)zinc(II)] bis(perchlorate)

被引:0
作者
Tian, Da-Min [1 ]
Shi, Chong-Yu [2 ]
机构
[1] Henan Univ Urban Construct, Dept Chem & Chem Engn, Pingdingshan 467044, Henan, Peoples R China
[2] Zhongzhou Univ, Zhongzhou 450044, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S160053681004479X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the centrosymmetric dinuclear title complex, [Zn-2(C13H19N4O)(2)(C2H5OH)(2)](ClO4)(2), the Zn-II atom is in a distorted trigonal-bipyramidal coordination geometry. The equatorial plane is constructed by one N atom and one O atom from two 1,3-bis(3,5-dimethylpyrazol-1-yl)propan-2-olate (bppo) ligands and one O atom from an ethanol molecule. One N atom and one O atom from the two bppo ligands occupy the axial positions. Intermolecular O-H center dot center dot center dot O hydrogen bonds between the ethanol molecules and perchlorate anions, and O center dot center dot center dot pi interactions between the perchlorate anions and pyrazole rings [O center dot center dot center dot centroid distances = 3.494 (3) and 3.413 (3) angstrom], lead to a chain structure along [010].
引用
收藏
页码:M1520 / U405
页数:11
相关论文
共 5 条
[1]  
[Anonymous], 2007, SMART SAINT
[2]  
Brandenburg K., 1999, DIAMOND
[3]   Pd(II) complexes containing N-alkyl-3-pyridine-5-trifluoromethyl pyrazole ligands:: Synthesis, NMR studies and X-ray crystal structures [J].
Montoya, Vanessa ;
Pons, Josefina ;
Garcia-Anton, Jordi ;
Solans, Xavier ;
Font-Bardia, Merce ;
Ros, Josep .
INORGANICA CHIMICA ACTA, 2007, 360 (02) :625-637
[4]  
Sheldrick G.M., 1996, SADABS
[5]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122