Defect induced ferromagnetism in carbon-doped ZnO thin films

被引:65
作者
Akbar, Sadaf [1 ]
Hasanain, S. K. [1 ]
Abbas, Manzar [2 ]
Ozcan, S. [3 ]
Ali, B. [4 ]
Shah, S. Ismat [4 ,5 ]
机构
[1] Quaid I Azam Univ, Dept Phys, Islamabad, Pakistan
[2] CIIT Ctr Hlth Res, Dept Phys, Islamabad, Pakistan
[3] Hacettepe Univ, Dept Engn Phys, TR-06800 Ankara, Turkey
[4] Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
[5] Univ Delaware, Dept Phys & Astron, Newark, DE 19716 USA
关键词
Thin films; Semiconductor; Point defects; Grain boundaries;
D O I
10.1016/j.ssc.2010.10.035
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We report on room temperature ferromagnetism in C-doped ZnO thin films prepared by electron beam evaporation Magnetization Hall effect X-ray photoemission spectroscopy (XPS) and X-ray diffraction studies have been conducted to investigate the source and nature of ferromagnetism in C-doped ZnO The samples were observed to have n-type conduction with the carrier concentration increasing with C doping XPS does not give any evidence for C substituted at the O site and is more consistent with the formation of C-O bonds and with the presence of C primarily in the +4 state It is suggested that the ferromagnetism originates in the development of Zn vacancies that are stabilized due to the incorporation of C in a high valence state (C4+) (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:17 / 20
页数:4
相关论文
共 17 条
[1]   Substrate dependence of preferred orientation in sol-gel-derived zinc oxide films [J].
Chakrabarti, S ;
Ganguli, D ;
Chaudhuri, S .
MATERIALS LETTERS, 2004, 58 (30) :3952-3957
[2]   Observation of ferromagnetism at room temperature in ZnO thin films [J].
Hong, Nguyen Hoa ;
Sakai, Joe ;
Brize, Virginie .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (03)
[3]   Sputtering of graphite in pulsed and continuous arc and spark discharges [J].
Khalid, Rahila ;
Yaqub, Kashif ;
Yaseen, Sumaira ;
Javeed, Sumera ;
Ashraf, Afshan ;
Janjua, Sohail Ahmad ;
Ahmad, Shoaib .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2007, 263 (02) :497-502
[4]   Room temperature ferromagnetism in chemically synthesized ZnO rods [J].
Kumar, Shalendra ;
Kim, Y. J. ;
Koo, B. H. ;
Gautam, S. ;
Chae, K. H. ;
Kumar, Ravi ;
Lee, C. G. .
MATERIALS LETTERS, 2009, 63 (02) :194-196
[5]   Absence of intrinsic ferromagnetic interactions of isolated and paired co dopant atoms in Zn1-xCoxO with high structural perfection [J].
Ney, A. ;
Ollefs, K. ;
Ye, S. ;
Kammermeier, T. ;
Ney, V. ;
Kaspar, T. C. ;
Chambers, S. A. ;
Wilhelm, F. ;
Rogalev, A. .
PHYSICAL REVIEW LETTERS, 2008, 100 (15)
[6]   Nanosized superparamagnetic precipitates in cobalt-doped ZnO [J].
Opel, M. ;
Nielsen, K. -W. ;
Bauer, S. ;
Goennenwein, S. T. B. ;
Cezar, J. C. ;
Schmeisser, D. ;
Simon, J. ;
Mader, W. ;
Gross, R. .
EUROPEAN PHYSICAL JOURNAL B, 2008, 63 (04) :437-444
[7]   Room-temperature ferromagnetism in carbon-doped ZnO [J].
Pan, H. ;
Yi, J. B. ;
Shen, L. ;
Wu, R. Q. ;
Yang, J. H. ;
Lin, J. Y. ;
Feng, Y. P. ;
Ding, J. ;
Van, L. H. ;
Yin, J. H. .
PHYSICAL REVIEW LETTERS, 2007, 99 (12)
[8]   NOVEL MECHANISM FOR HIGH-SPEED GROWTH OF TRANSPARENT AND CONDUCTING TIN OXIDE THIN-FILMS BY SPRAY-PYROLYSIS [J].
RAO, LK ;
VINNI, V .
APPLIED PHYSICS LETTERS, 1993, 63 (05) :608-610
[9]   p-type conduction in unintentional carbon-doped ZnO thin films [J].
Tan, S. T. ;
Sun, X. W. ;
Yu, Z. G. ;
Wu, P. ;
Lo, G. Q. ;
Kwong, D. L. .
APPLIED PHYSICS LETTERS, 2007, 91 (07)
[10]   THE NATURE OF EXCESS OXYGEN IN CO3O4+EPSILON [J].
TYULIEV, G ;
ANGELOV, S .
APPLIED SURFACE SCIENCE, 1988, 32 (04) :381-391