Photoinduced Acetylation of Anilines under Aqueous and Catalyst-Free Conditions

被引：6
|
作者：
Yang, Yu-Ming [1 ,2 ]
Yan, Wei [2 ]
Hu, Han-Wei [1 ]
Luo, Yimin [3 ]
Tang, Zhen-Yu [1 ,2 ]
Luo, Zhuangzhu [3 ]
机构：
[1] Sun Yat Sen Univ, Sch Pharmaceut Sci Shenzhen, Guangzhou 510275, Peoples R China
[2] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
[3] Sun Yat Sen Univ, Sch Mat, Guangzhou 510275, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 17期
基金：
中国国家自然科学基金;
关键词：
VISIBLE-LIGHT PHOTOREDOX; METAL-FREE; ORGANIC-REACTIONS; DIAZONIUM SALTS; SELECTIVE HALOGENATION; ARYL DIAZONIUM; ONE-POT; TRIFLUOROMETHYLATION; DERIVATIVES; WATER;
D O I：
10.1021/acs.joc.1c01290
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A green and efficient visible-light induced functionalization of anilines under mild conditions has been reported. Utilizing nontoxic, cost-effective, and water-soluble diacetyl as photosensitizer and acetylating reagent, and water as the solvent, a variety of anilines were converted into the corresponding aryl ketones, iodides, and bromides. With advantages of environmentally friendly conditions, simple operation, broad substrate scope, and functional group tolerance, this reaction represents a valuable method in organic synthesis.
引用
收藏
页码：12344 / 12353
页数：10
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