Synthesis and Crystal Structure of [W3S4(Acac)3(PPh3)3]PF6 • 0.5CHCl3 and [W3S4(Hfac)3(PPh3)2Br] • 2CHCl3

被引：0

作者：

Adonin, S. A. ^{[1
]}

Virovets, A. V. ^{[1
]}

Sokolov, M. N. ^{[1
,2
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

CLUSTERS;

D O I：

10.1134/S1070328410100027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New cluster complexes [W3S4(Acac)(3)(PPh3)(3)]PF6 center dot 0.5CHCl(3) (Acac = CH3C(O)CHC(O)CH3) (I) and [W3S4(Hfac)(3)(PPh3)(2)Br] center dot 2CHCl(3) (Hfac = CF3C(O)CHC(O)CF3) (II) were synthesized. Their molecular and crystal structures were determined by X-ray diffraction. The cis-cis type of coordination of acetylacetonate and hexafluoroacetylacetonate ligands in I and II, respectively, was established, and the PPh3 ligands were found in the trans-positions with respect to the "capping" sulfide ligand (mu(3)-S).

引用

页码：734 / 738

页数：5

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