Hydrothermal Synthesis and Crystal Structure of a Zinc(II) Coordination Polymer Assembled by Dpphen and H2btec/btec

被引：0
作者：
Li Xiu-Mei [1 ]
Niu Yan-Ling [1 ]
Wang Qing-Wei [2 ]
Liu Bo [2 ]
机构：
[1] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Jilin, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 07期
关键词：
hydrogen bond; crystal structure; coordination polymer; NITROGEN-DONOR LIGANDS; CHEMISTRY; COMPLEXES; FRAMEWORKS; SORPTION; SOLIDS; DESIGN;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new metal-organic coordination polymer [Zn-2(dpphen)(2)(H(2)btec)(btec)(0.5)]n (dpphen = 4,7-diphenyl-1,10-phenanthroline, H(4)btec = 1,2,4,5-benzenetetracarboxylic acid) 1 was obtained via hydrothermal synthesis and characterized by elemental analysis, TG, IR spectrum and single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2(1)/n with a = 16.2996(14), b = 14.3332(12), c = 25.247(2) angstrom, beta = 103.4050(10)degrees, V = 5737.7(9) angstrom(3), C63H37N4O12Zn2, M-r = 1172.71, D-c = 1.358 g/cm(3), mu(MoKa) = 0.902 mm(-1), F(000) = 2396, Z = 4, the final R = 0.0684 and wR = 0.1281 for 3728 observed reflections (I > 2 sigma(I)). It exhibits a two-dimensional network structure constructed by mixed ligands of dpphen and H(2)btec/btec.
引用
收藏
页码：1122 / 1126
页数：5
相关论文
共 22 条
  • [1] [Anonymous], 1988, WINDOWS PROGRAM CRYS
  • [2] [Anonymous], 1997, SHELXS 97 PROGRAM RE
  • [3] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
  • [4] 2-Z
  • [5] Inorganic crystal engineering using self-assembly of tailored building-blocks
    Blake, AJ
    Champness, NR
    Hubberstey, P
    Li, WS
    Withersby, MA
    Schröder, M
    [J]. COORDINATION CHEMISTRY REVIEWS, 1999, 183 : 117 - 138
  • [6] Polycatenation, polythreading and polyknotting in coordination network chemistry
    Carlucci, L
    Ciani, G
    Proserpio, DM
    [J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 247 - 289
  • [7] Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4'-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands
    Devereux, Michael
    Shea, Denis O.
    Kellett, Andrew
    McCann, Malachy
    Walsh, Maureen
    Egan, Denise
    Deegan, Carol
    Kgdziora, Kinga
    Rosair, Georgina
    Muelller-Bunz, Helge
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 2007, 101 (06) : 881 - 892
  • [8] Supramolecular coordination chemistry and functional microporous molecular materials
    Dinolfo, PH
    Hupp, JT
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (10) : 3113 - 3125
  • [9] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks
    Eddaoudi, M
    Moler, DB
    Li, HL
    Chen, BL
    Reineke, TM
    O'Keeffe, M
    Yaghi, OM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) : 319 - 330
  • [10] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry
    Férey, G
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (10) : 3084 - 3098
123