A self-assembling hexameric spheroid with variable degrees of hydration

被引：3

作者：

Ashmore, Jason ^{[1
]}

Bishop, Roger ^{[1
]}

Craig, Donald C. ^{[1
]}

Scudder, Marcia L. ^{[1
]}

机构：

[1] Univ New S Wales UNSW, Sch Chem, Sydney, NSW 2052, Australia

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2011年 / 71卷 / 3-4期

基金：

澳大利亚研究理事会;

关键词：

Inclusion compounds; Hydrate; X-ray crystal structures; Spheroidal structure; Variable composition; INCLUSION; HOST;

D O I：

10.1007/s10847-011-9943-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The V-shaped racemic compound 4,12-dinitro-6,7,14,15-tetrahydro-6,14-methanocycloocta[1,2-b:5,6-b'] diquinoline 2 crystallises from solvents of differing water content as a centrosymmetric spheroidal hexamer in the form of a series of isostructural clusters (2)(6)center dot(water)(x) X-ray structures of these crystals in space group R (3) over bar show that they can exhibit an extent of hydration anywhere throughout the composition range x = 0 to 1.

引用

页码：297 / 302

页数：6

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