A Copper Porphyrin for Sensing H2S in Aqueous Solution via a "Coordinative-Based" Approach

被引：44

作者：

Mirra, Silvia ^{[1
]}

Milione, Stefano ^{[1
]}

Strianese, Maria ^{[1
]}

Pellecchia, Claudio ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim & Biol, I-84084 Fisciano, SA, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 13期

关键词：

Fluorescence; Sensors; Hydrogen sulfide; Porphyrinoids; Copper; RATIOMETRIC FLUORESCENT-PROBE; ENDOGENOUS HYDROGEN-SULFIDE; QUANTITATIVE DETECTION; SENSOR; CHEMOSENSOR; COMPLEX; ROLES;

D O I：

10.1002/ejic.201500070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A turn on fluorescence-based probe for sensing H2S in water via a coordinative-based approach has been successfully devised. The probe can selectively detect H2S in aqueous solutions over other anions, biothiols, and common oxidants such as H2O2. H-1 NMR spectroscopy and ESI-MS experiments provide evidence that the turn-on response in the presence of H2S is due to binding of the target anion to the copper center.

引用

页码：2272 / 2276

页数：5

共 54 条

[21] Capture and Visualization of Hydrogen Sulfide by a Fluorescent Probe [J].

Liu, Chunrong ;

Pan, Jia ;

Li, Sheng ;

Zhao, Yu ;

Wu, Lisa Y. ;

Berkman, Clifford E. ;

Whorton, A. Richard ;

Xian, Ming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (44) :10327-10329

[22] A Ratiometric Fluorescent Probe for Biological Signaling Molecule H2S: Fast Response and High Selectivity [J].

Liu, Jing ;

Sun, Yuan-Qiang ;

Zhang, Jingyu ;

Yang, Ting ;

Cao, Jianbin ;

Zhang, Lishen ;

Guo, Wei .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (15) :4717-4722

[23] Heterogeneous Nano Metal-Organic Framework Fluorescence Probe for Highly Selective and Sensitive Detection of Hydrogen Sulfide in Living Cells [J].

Ma, Yu ;

Su, Hao ;

Kuang, Xuan ;

Li, Xiangyuan ;

Zhang, Tingting ;

Tang, Bo .

ANALYTICAL CHEMISTRY, 2014, 86 (22) :11459-11463

[24] High-Sensitivity Naphthalene-Based Two-Photon Fluorescent Probe Suitable for Direct Bioimaging of H2S in Living Cells [J].

Mao, Guo-Jiang ;

Wei, Tian-Tian ;

Wang, Xu-Xiang ;

Huan, Shuang-yan ;

Lu, Dan-Qing ;

Zhang, Jing ;

Zhang, Xiao-Bing ;

Tan, Weihong ;

Shen, Guo-Li ;

Yu, Ru-Qin .

ANALYTICAL CHEMISTRY, 2013, 85 (16) :7875-7881

[25] Selective turn-on fluorescent probes for imaging hydrogen sulfide in living cells [J].

Montoya, Leticia A. ;

Pluth, Michael D. .

CHEMICAL COMMUNICATIONS, 2012, 48 (39) :4767-4769

[26] ABSORPTION SPECTRA OF PORPHYRIN-A AND DERIVATIVES [J].

OLIVER, IT ;

RAWLINSON, WA .

BIOCHEMICAL JOURNAL, 1955, 61 (04) :641-646

[27] Hydrosulfide (HS-) Coordination in Iron Porphyrinates [J].

Pavlik, Jeffrey W. ;

Noll, Bruce C. ;

Oliver, Allen G. ;

Schulz, Charles E. ;

Scheidt, W. Robert .

INORGANIC CHEMISTRY, 2010, 49 (03) :1017-1026

[28] A Fluorescent Probe for Fast and Quantitative Detection of Hydrogen Sulfide in Blood [J].

Peng, Hanjing ;

Cheng, Yunfeng ;

Dai, Chaofeng ;

King, Adrienne L. ;

Predmore, Benjamin L. ;

Lefer, David J. ;

Wang, Binghe .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (41) :9672-9675

[29] Factors Controlling the Reactivity of Hydrogen Sulfide with Hemeproteins [J].

Pietri, Ruth ;

Lewis, Ariel ;

Leon, Ruth G. ;

Casabona, Gullermina ;

Kiger, Laurent ;

Yeh, Syun-Ru ;

Fernandez-Alberti, Sebastian ;

Marden, Michael C. ;

Cadilla, Carmen L. ;

Lopez-Garriga, Juan .

BIOCHEMISTRY, 2009, 48 (22) :4881-4894

[30] Selective fluorescent probes for live-cell monitoring of sulphide [J].

Qian, Yong ;

Karpus, Jason ;

Kabil, Omer ;

Zhang, Shu-Yu ;

Zhu, Hai-Liang ;

Banerjee, Ruma ;

Zhao, Jing ;

He, Chuan .

NATURE COMMUNICATIONS, 2011, 2

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