A Copper Porphyrin for Sensing H2S in Aqueous Solution via a "Coordinative-Based" Approach

被引：44

作者：

Mirra, Silvia ^{[1
]}

Milione, Stefano ^{[1
]}

Strianese, Maria ^{[1
]}

Pellecchia, Claudio ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim & Biol, I-84084 Fisciano, SA, Italy

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 13期

关键词：

Fluorescence; Sensors; Hydrogen sulfide; Porphyrinoids; Copper; RATIOMETRIC FLUORESCENT-PROBE; ENDOGENOUS HYDROGEN-SULFIDE; QUANTITATIVE DETECTION; SENSOR; CHEMOSENSOR; COMPLEX; ROLES;

D O I：

10.1002/ejic.201500070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A turn on fluorescence-based probe for sensing H2S in water via a coordinative-based approach has been successfully devised. The probe can selectively detect H2S in aqueous solutions over other anions, biothiols, and common oxidants such as H2O2. H-1 NMR spectroscopy and ESI-MS experiments provide evidence that the turn-on response in the presence of H2S is due to binding of the target anion to the copper center.

引用

页码：2272 / 2276

页数：5

共 54 条

[1] Quantitative 1H NMR analysis of alkaline polysulfide solutions [J].

Argyropoulos, DS ;

Hou, YH ;

Ganesaratnam, R ;

Harpp, DN ;

Koda, K .

HOLZFORSCHUNG, 2005, 59 (02) :124-131

[2] A Near-Infrared Fluorescence Turn-On Sensor for Sulfide Anions [J].

Cao, Xiaowei ;

Lin, Weiying ;

He, Longwei .

ORGANIC LETTERS, 2011, 13 (17) :4716-4719

[3] Hydrogen sulfide: third gaseous transmitter, but with great pharmacological potential [J].

Chen, Chang-qing ;

Xin, Hong ;

Zhu, Yi-zhun .

ACTA PHARMACOLOGICA SINICA, 2007, 28 (11) :1709-1716

[4] Reaction-Based Genetically Encoded Fluorescent Hydrogen Sulfide Sensors [J].

Chen, Si ;

Chen, Zhi-jie ;

Ren, Wei ;

Ai, Hui-wang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (23) :9589-9592

[5] A red emission fluorescent probe for hydrogen sulfide and its application in living cells imaging [J].

Chen, Tao ;

Zheng, Yi ;

Xu, Zhaochao ;

Zhao, Miao ;

Xu, Yongnan ;

Cui, Jingnan .

TETRAHEDRON LETTERS, 2013, 54 (23) :2980-2982

[6] Sulfide-selective chemosignaling by a Cu2+ complex of dipicolylamine appended fluorescein [J].

Choi, Myung Gil ;

Cha, Sunyoung ;

Lee, Haekyung ;

Jeon, Hye Lim ;

Chang, Suk-Kyu .

CHEMICAL COMMUNICATIONS, 2009, (47) :7390-7392

[7] A small molecule two-photon probe for hydrogen sulfide in live tissues [J].

Das, Sajal Kumar ;

Lim, Chang Su ;

Yang, Sun Young ;

Han, Ji Hee ;

Cho, Bong Rae .

CHEMICAL COMMUNICATIONS, 2012, 48 (67) :8395-8397

[8] SPECTRA OF THE METALLO-DERIVATIVES OF ALPHA,BETA,GAMMA,OMEGA-TETRAPHENYLPORPHINE [J].

DOROUGH, GD ;

MILLER, JR ;

HUENNEKENS, FM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (09) :4315-4320

[9] Spectral monitoring of the formation and degradation of polysulfide ions in alkaline conditions [J].

Filpponen, Ilari ;

Guerra, Anderson ;

Hai, Abdul ;

Lucia, n A. Lucia ;

Argyropoulos, Dimitris S. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (22) :7388-7392

[10]

Glazkov Yu. V., 1981, Journal of Applied Spectroscopy, V35, P1254, DOI 10.1007/BF00624125

← 1 2 3 4 5 6 →