[C10N2H10][ZnCl(HPO4)]2:: A new templated zincophosphate containing tetrahedral nets with 63 topology

被引：9
|
作者：
Natarajan, S [1 ]
Ewald, B [1 ]
Prots, Y [1 ]
Kniep, R [1 ]
机构：
[1] Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 09期
关键词：
zincophosphate; chloride-substitution; layer structure; templates;
D O I：
10.1002/zaac.200500062
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of [C10N2H10][ZnCl(HPO4)](2) contains corrugated tetrahedral layers (2)(infinity)[ZnCl(HPO4)(-)] with 6(3) topology. Charge balance is achieved by insertion of diprotonated 4,4'-bipyridine between the layers. Crystal data: monoclinic, P2(1)/n (no. 14), a = 4.8832(2) angstrom, b = 22.673(2) angstrom, c = 8.1643(4) angstrom, beta = 104.02(1)degrees; V = 877.0(1) angstrom(3); Z = 4; R1 = 0.041 and wR2 = 0.088 for 1836 reflections [I > 2 sigma(I)]. Tetrahedral layers (2)(infinity)[ZnCl(HPO4)(-)] are also observed in other organo-ammonium templated compounds. However, their topologies are characterized by 4.8(2) nets. With the title compound a layered tetrahedral net (2)(infinity)[ZnCl(HPO4)(-)] with 6(3)-topology is reported for the first time.
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收藏
页码：1622 / 1626
页数：5
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