Elasticity of the spatial network of hydrogen bonds in liquids

被引:0
作者
Rodnikova, MN [1 ]
Val'kovskaya, TM
Kartsev, VN
Kayumova, DB
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
[2] Saratov NG Chernyshevskii State Univ, Phys Res Inst, Saratov, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2003年 / 77卷 / 10期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A large body of experimental data on the isothermal compressibility of diamines, diols, amino alcohols, and light and heavy water obtained on a unique direct-compression setup was used to estimate the elasticity of the space network of hydrogen bonds of these substances. An inverse dependence of the modulus of all-round compression on a number of defects in the three-dimensional network was discovered. A comparison was made with the isothermal compressibility of liquids without the H-bond space network: liquid alkanes, aliphatic alcohols, benzene, and carbon tetrachloride.
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页码:1725 / 1726
页数:2
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