Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!

被引：68
作者：
Fromm, Katharina M. [1 ]
机构：
[1] Univ Fribourg, Dept Chem, Chemin Musee 9, CH-1700 Fribourg, Switzerland
来源：
COORDINATION CHEMISTRY REVIEWS | 2020年 / 408卷
基金：
瑞士国家科学基金会;
关键词：
COORDINATION POLYMER NETWORKS; HEAVY GRIGNARD-REAGENTS; CRYSTAL-STRUCTURES; MAGNESIUM(I) COMPOUNDS; BERYLLIUM CHEMISTRY; MOLECULAR-STRUCTURE; VOLATILE ALKALINE; COMPLEXES; BARIUM; CALCIUM;
D O I：
10.1016/j.ccr.2020.213193
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Some scientists might consider group 2 chemistry as "boring, closed shell and all ionic, aqueous chemistry, where everything is known! It is not worth investigating". How wrong they are! Far from forming only purely ionic compounds, this review will shed light on some spectacular molecules, showing that alkaline earth metal ions can behave similar to transition metal ions. After general remarks about each element, from beryllium to barium, mainly recent examples of group 2 coordination compounds will be presented, their bonding situation will be discussed and examples of applications, e.g. in catalysis, will be given. (C) 2020 Elsevier B.V. All rights reserved.
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页数：22
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  • [21] Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis
    Dange, Deepak
    Gair, Andrew R.
    Jones, Dafydd D. L.
    Juckel, Martin
    Aldridge, Simon
    Jones, Cameron
    [J]. CHEMICAL SCIENCE, 2019, 10 (11) : 3208 - 3216
  • [22] Alkali and Alkaline Earth Metal Derivatives of Disila-Bridged Podands: Coordination Chemistry and Structural Diversity
    Dankert, Fabian
    Donsbach, Carsten
    Mais, Christopher-Nils
    Reuter, Kirsten
    von Haenisch, Carsten
    [J]. INORGANIC CHEMISTRY, 2018, 57 (01) : 351 - 359
  • [23] Aminotroponiminate calcium and strontium complexes
    Datta, Simmi
    Gamer, Michael T.
    Roesky, Peter W.
    [J]. DALTON TRANSACTIONS, 2008, (21) : 2839 - 2843
  • [24] Complexation of some alkali and alkaline earth metal cations by macrocyclic compounds containing four pyridine subunits - a DFT study
    Despotovic, Ines
    [J]. NEW JOURNAL OF CHEMISTRY, 2015, 39 (08) : 6151 - 6162
  • [25] Calcium formamidinate derivatives by hydride insertion of carbodiimides
    Dyall, Joshua
    Hill, Michael S.
    Mahon, Mary F.
    Teh, Luke
    Wilson, Andrew S. S.
    [J]. DALTON TRANSACTIONS, 2019, 48 (13) : 4248 - 4254
  • [26] Synthesis Target Structures for Alkaline Earth Oxide Clusters
    Escher, Susanne G. E. T.
    Lazauskas, Tomas
    Zwijnenburg, Martijn A.
    Woodley, Scott M.
    [J]. INORGANICS, 2018, 6 (01):
  • [27] A nearly planar water sheet sandwiched between strontium-imidazolium carboxylate coordination polymers
    Fei, ZF
    Geldbach, TJ
    Zhao, DB
    Scopelliti, R
    Dyson, PJ
    [J]. INORGANIC CHEMISTRY, 2005, 44 (15) : 5200 - 5202
  • [28] Compartmentalization of Alkaline-Earth Metals in Salen-Type Cu-and Ni-Complexes in Solution and in the Solid State
    Finelli, Alba
    Herault, Nelly
    Crochet, Aurelien
    Fromm, Katharina M.
    [J]. ACS OMEGA, 2019, 4 (06): : 10231 - 10242
  • [29] Structure-Solubility Relationship of 1,4-Dioxane Complexes of Di(hydrocarbyl)magnesium
    Fischer, Reinald
    Goerls, Helmar
    Meisinger, Philippe R.
    Suxdorf, Regina
    Westerhausen, Matthias
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (55) : 12830 - 12841
  • [30] Selective modification of the metal coordination environment in heavy alkaline-earth iodide complexes
    Fitts, Lacey S.
    Bierschenk, Eric J.
    Hanusa, Timothy P.
    Rheingold, Arnold L.
    Pink, Maren
    Young, Victor G., Jr.
    [J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (10) : 8229 - 8238
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