Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!

被引：68
作者：
Fromm, Katharina M. [1 ]
机构：
[1] Univ Fribourg, Dept Chem, Chemin Musee 9, CH-1700 Fribourg, Switzerland
来源：
COORDINATION CHEMISTRY REVIEWS | 2020年 / 408卷
基金：
瑞士国家科学基金会;
关键词：
COORDINATION POLYMER NETWORKS; HEAVY GRIGNARD-REAGENTS; CRYSTAL-STRUCTURES; MAGNESIUM(I) COMPOUNDS; BERYLLIUM CHEMISTRY; MOLECULAR-STRUCTURE; VOLATILE ALKALINE; COMPLEXES; BARIUM; CALCIUM;
D O I：
10.1016/j.ccr.2020.213193
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Some scientists might consider group 2 chemistry as "boring, closed shell and all ionic, aqueous chemistry, where everything is known! It is not worth investigating". How wrong they are! Far from forming only purely ionic compounds, this review will shed light on some spectacular molecules, showing that alkaline earth metal ions can behave similar to transition metal ions. After general remarks about each element, from beryllium to barium, mainly recent examples of group 2 coordination compounds will be presented, their bonding situation will be discussed and examples of applications, e.g. in catalysis, will be given. (C) 2020 Elsevier B.V. All rights reserved.
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页数：22
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