Crystal structure of [ZnH(NPMe3)]4, a tetrameric phosphoraneiminato complex of zinc with terminal hydride ligands

被引：0

作者：

Krieger, M ^{[1
]}

Neumuller, B ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 10期

关键词：

zinc; phosphoraneiminato complex; hydrido compound; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199810)624:10<1563::AID-ZAAC1563>3.3.CO;2-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the title compound, which crystallizes as [ZnH(NPMe3)](4). 4THF forming colourless, very reactive blocks, obtained by recrystallization from toluene, reveals discrete tetrameric molecules with heterocubane structure with almost undistorted Zn4N4 cubic skeletons. The hydride ligands assume terminal exocyclic positions with Zn-H bond lengths of 150 pm in average.

引用

页码：1563 / 1564

页数：2