Crystal structure of [ZnH(NPMe3)]4, a tetrameric phosphoraneiminato complex of zinc with terminal hydride ligands

被引：0

作者：

Krieger, M ^{[1
]}

Neumuller, B ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 10期

关键词：

zinc; phosphoraneiminato complex; hydrido compound; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199810)624:10<1563::AID-ZAAC1563>3.3.CO;2-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the title compound, which crystallizes as [ZnH(NPMe3)](4). 4THF forming colourless, very reactive blocks, obtained by recrystallization from toluene, reveals discrete tetrameric molecules with heterocubane structure with almost undistorted Zn4N4 cubic skeletons. The hydride ligands assume terminal exocyclic positions with Zn-H bond lengths of 150 pm in average.

引用

页码：1563 / 1564

页数：2

共 50 条

[21] Crystal structure and spectral characterization of a rare example of a salen-type zinc complex with neutral monodentate oxygen donor ligands coordination
Kaczmarek, Malgorzata T.
Kubicki, Maciej
Radecka-Paryzek, Wanda
MONATSHEFTE FUR CHEMIE, 2006, 137 (08): : 997 - 1003
[22] Hydrothermal Synthesis, Crystal Structure of Zinc(II) Complex of bis(2-Benzimidazole) and Aromatic Carboxylate Ligands
Feng, Guo-Dong
Jiang, Luan
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (03) : 1348 - 1350
[23] Synthesis and crystal structure of dinuclear zinc(II) complex with 3-Me-N-oxopyridine-2-thiol
Niu, DZ
Sun, BW
Lu, ZS
Song, BL
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (02) : 108 - 111
[24] Lanthanide Terminal Hydride Complexes Bearing Two Sterically Demanding C5Me4SiMe3 Ligands. Synthesis, Structure, and Reactivity
Takenaka, Yasumasa
Hou, Zhaomin
ORGANOMETALLICS, 2009, 28 (17) : 5196 - 5203
[25] Synthesis and Crystal Structure of Dinuclear Zinc(II) Complex with 3-Me-N-oxopyridine-2-thiol
NIU De-Zhong SUN Bai-Wang LU Zai-Sheng SONG Bao-Lin \$(Department of Chemistry
结构化学, 2001, (02) : 108 - 111
[26] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TETRAMERIC NITRIDO COMPLEX [CU(CH3CN)4]2[W4N4CL14(CH3CN)2]
NEUHAUS, A
DEHNICKE, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (04): : 775 - 778
[27] Synthesis, Crystal Structure of Zinc Complex with 3-Hydroxy-1-adamantanecarboxylic Acid
Zhao, Guo-Liang
Wu, Xiao-Yong
Guan, Quan-Yin
Shen, Jin-Bei
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (06) : 2447 - 2449
[28] Crystal structure of a homoleptic zinc(II) complex based on bis(3,5-diisopropylpyrazol-1-yl)acetate
Elsberg, Josiah G.
Spiropulos, Nicholas G.
Colson, Adam C.
Brown, Eric C.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1259 - +
[29] Synthesis and Crystal Structure of a New Cobalt Complex Based on 5-Bromoisophthalate and 4,4′-Dipyridyldisulfide Ligands
Qin, Jian-Hua
Wang, Jian-Ge
Hu, Yue
Ma, Lu-Fang
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (05) : 552 - 555
[30] Phosphaneimine and phosphoraneiminato complexes of zinc. Crystal structures of [ZnCl2(Me(3)SiNP(CH2)(4)CMe(3))](2), [ZnI2(Me(3)SiNPEt(3))](2), [ZnI2{Me(2)Si(NPEt(3))(2)}], and [ZnBr(NPMe(3))](4)center dot CH2Cl2
Krieger, M
Harms, K
Magull, J
Dehnicke, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (02): : 243 - 250

← 1 2 3 4 5 →