Biomass Porous Carbons Derived from Banana Peel Waste as Sustainable Anodes for Lithium-Ion Batteries

被引:30
作者
Luna-Lama, Fernando [1 ]
Morales, Julian [1 ]
Caballero, Alvaro [1 ]
机构
[1] Univ Cordoba, Inst Univ Quim Fina & Nanoquim IUNAN, Dept Quim Inorgan & Ingn Quim, Fac Ciencias, Cordoba 14071, Spain
关键词
banana peel waste; biomass; anode; Li-ion batteries; ELECTROCHEMICAL PERFORMANCE; ENERGY-STORAGE; MICROPOROUS CARBON; ACTIVATED CARBON; HARD CARBONS; CAPACITY; SUPERCAPACITORS; PYROLYSIS; INSERTION; SHELLS;
D O I
10.3390/ma14205995
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Disordered carbons derived from banana peel waste (BPW) were successfully obtained by employing a simple one-step activation/carbonization method. Different instrumental techniques were used to characterize the structural, morphological, and textural properties of the materials, including X-ray diffraction, thermogravimetric analysis, porosimetry and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The chemical activation with different porogens (zinc chloride, potassium hydroxide and phosphoric acid) could be used to develop functional carbonaceous structures with high specific surface areas and significant quantities of pores. The BPW@H3PO4 carbon exhibited a high specific surface area (815 m(2) g(-1)), chemical stability and good conductivity for use as an anode in lithium-ion batteries. After 200 cycles, this carbon delivered a reversible capacity of 272 mAh g(-1) at 0.2 C, showing a notable retention capacity and good cycling performance even at high current densities, demonstrating its effectiveness and sustainability as an anode material for high-energy applications in Li-ion batteries.</p>
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页数:19
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