We have studied the photoconductivity spectrum, thermally stimulated current, current-light characteristics, and temperature-dependent photocurrent in Bridgman-grown ordered-vacancy Ga2Se3 crystals. The observed temperature quenching of photoconductivity and two regions of its thermal activation in Ga2Se3 crystals are interpreted in terms of a multicenter recombination model which incorporates an s-channel of active recombination, r-centers of photosensitivity, and traps for nonequilibrium majority carriers.