Manganese-New prominent actor in transfer hydrogenation catalysis

被引：44
作者：
Azouzi, Karim [1 ]
Valyaev, Dmitry A. [1 ]
Bastin, Stephanie [1 ]
Sortais, Jean-Baptiste [1 ,2 ]
机构：
[1] Univ Toulouse, UPS, CNRS, LCC CNRS, 205 Route Narbonne, F-31077 Toulouse 4, France
[2] Inst Univ France, 1 Rue Descartes, F-75231 Paris 5, France
来源：
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY | 2021年 / 31卷
关键词：
ASYMMETRIC TRANSFER HYDROGENATION; STEREOSELECTIVE TRANSFER SEMIHYDROGENATION; KETONES; ALCOHOLS; ALKYNES;
D O I：
10.1016/j.cogsc.2021.100511
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transfer hydrogenation processes catalyzed by manganese organometallic complexes are comprehensively reviewed. The reaction scope includes the reduction of aldehydes, ketones, imines, polyaromatic nitrogen heterocycles, esters, nitriles, and semihydrogenation of internal alkynes. Special attention is devoted to ligand design for Mn-catalyzed asymmetric transfer hydrogenation of prochiral ketones leading to enantiomerically enriched alcohols.
引用
收藏
页数：7
相关论文
共 39 条
  • [1] Asymmetric transfer hydrogenation of ketones promoted by manganese(I) pre-catalysts supported by bidentate aminophosphines
    Azouzi, Karim
    Bruneau-Voisine, Antoine
    Vendier, Laure
    Sortais, Jean-Baptiste
    Bastin, Stephanie
    [J]. CATALYSIS COMMUNICATIONS, 2020, 142 (142)
  • [2] Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst
    Bruneau-Voisine, Antoine
    Wang, Ding
    Dorcet, Vincent
    Roisnel, Thierry
    Darcel, Christophe
    Sortais, Jean-Baptiste
    [J]. ORGANIC LETTERS, 2017, 19 (13) : 3656 - 3659
  • [3] Mono-N-methylation of anilines with methanol catalyzed by a manganese pincer-complex
    Bruneau-Voisine, Antoine
    Wang, Ding
    Dorcet, Vincent
    Roisnel, Thierry
    Darcel, Christophe
    Sortais, Jean-Baptiste
    [J]. JOURNAL OF CATALYSIS, 2017, 347 : 57 - 62
  • [4] Highly Chemo- and Stereoselective Transfer Semihydrogenation of Alkynes Catalyzed by a Stable, Well-Defined Manganese(II) Complex
    Brzozowska, Aleksandra
    Azofra, Luis Miguel
    Zubar, Viktoriia
    Atodiresei, Iuliana
    Cavallo, Luigi
    Rueping, Magnus
    El-Sepelgy, Osama
    [J]. ACS CATALYSIS, 2018, 8 (05): : 4103 - 4109
  • [5] Asymmetric Transfer Hydrogenation of Ketones with Well-Defined Manganese(I) PNN and PNNP Complexes
    Demmans, Karl Z.
    Olson, Maxwell E.
    Morris, Robert H.
    [J]. ORGANOMETALLICS, 2018, 37 (24) : 4608 - 4618
  • [6] Transfer Hydrogenation of Carbonyl Groups, Imines and N-Heterocycles Catalyzed by Simple, Bipyridine-Based MnI Complexes
    Dubey, Abhishek
    Rahaman, S. M. Wahidur
    Fayzullin, Robert R.
    Khusnutdinova, Julia R.
    [J]. CHEMCATCHEM, 2019, 11 (16) : 3844 - 3852
  • [7] Catalytic (de)hydrogenation promoted by non-precious metals - Co, Fe and Mn: recent advances in an emerging field
    Filonenko, Georgy A.
    van Putten, Robbert
    Hensen, Emiel J. M.
    Pidko, Evgeny A.
    [J]. CHEMICAL SOCIETY REVIEWS, 2018, 47 (04) : 1459 - 1483
  • [8] Cooperative Mn(i)-complex catalyzed transfer hydrogenation of ketones and imines
    Ganguli, Kasturi
    Shee, Sujan
    Panja, Dibyajyoti
    Kundu, Sabuj
    [J]. DALTON TRANSACTIONS, 2019, 48 (21) : 7358 - 7366
  • [9] Manganese-Catalyzed Transfer Hydrogenation of Nitriles with 2-Butanol as the Hydrogen Source
    Garduno, Jorge A.
    Flores-Alamo, Marcos
    Garcia, Juventino J.
    [J]. CHEMCATCHEM, 2019, 11 (21) : 5330 - 5338
  • [10] HADDAD YMY, 1964, P CHEM SOC LONDON, P361
1234