Synthesis of selectively permodified γ-cyclodextrins.: A new set of chiral stationary phases in capillary GC.

被引：9

作者：

Cravotto, G

Palmisano, G

Panza, L

Tagliapietra, S

机构：

[1] Dipartimento Sci & Tecnol Farmaco, I-10125 Turin, Italy

[2] Univ Insubria, Dipartimento Sci Chim Fis & Matemat, I-22100 Como, Italy

[3] Dipartimento Sci Chim Alimentari Farmaceut & Farm, I-28100 Novara, Italy

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2000年 / 19卷 / 09期

关键词：

D O I：

10.1080/07328300008544147

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Two pairs of new chiral selectors, derived from octakis(6-O-t-butyldimethylsilyl)- and octakis(6-O-t-hexyldimethylsilyl)-gamma -cyclodextrin, were synthesized with inverse substitution patterns at the secondary positions. 2-O-methyl-3-O-acetyl- and 2-O-acetyl-3-O-methyl derivatives are suggested as useful models to further investigate the effect of substituents at C-2 and C-3 on the efficiency of enantioseparation using gas chromatography.

引用

页码：1235 / 1245

页数：11