Synthesis and spectra of N-15 labelled phenylazides

被引：11

作者：

Leseticky, L ^{[1
]}

Barth, R ^{[1
]}

Nemec, I ^{[1
]}

Stícha, M ^{[1
]}

Tislerová, I ^{[1
]}

机构：

[1] Charles Univ, Fac Sci, CZ-12840 Prague 2, Czech Republic

来源：

CZECHOSLOVAK JOURNAL OF PHYSICS | 2003年 / 53卷

关键词：

D O I：

10.1007/s10582-003-0101-0

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Phenylazides labelled with N-15 in different positions were synthesised by methods that allow the stepwise introduction of nitrogen atoms. El MS, IR and NMR spectra were measured that confirmed the high purity and identity all isotopomers.

引用

页码：A777 / A782

页数：6

共 16 条

[1] The interplay of theory and experiment in the study of phenylnitrene [J].

Borden, WT ;

Gritsan, NP ;

Hadad, CM ;

Karney, WL ;

Kemnitz, CR ;

Platz, MS .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (11) :765-771

[2]

Bretschneider H., 1950, Monatsh. Chem, V81, P970, DOI [10.1007/BF00899340, DOI 10.1007/BF00899340]

[3] Pentazole chemistry:: the mechanism of the reaction of aryldiazonium chlorides with azide ion at -80 °C:: concerted versus stepwise formation of arylpentazoles, detection of a pentazene intermediate, a combined 1H and 15N NMR experimental and ab initio theoretical study [J].

Butler, RN ;

Fox, A ;

Collier, S ;

Burke, LA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (10) :2243-2247

[4] REAKTIONEN MIT N-15 .6. ZUR STRUKTUR DES PHENYLAZIDS [J].

CLUSIUS, K ;

WEISSER, HR .

HELVETICA CHIMICA ACTA, 1952, 35 (05) :1548-1559

[5] REAKTIONEN MIT N-15 .11. ZUR BILDUNG VON PHENYLAZID AUS PHENYLDIAZONIUMPERBROMID UND AMMONIAK [J].

CLUSIUS, K ;

HURZELER, H .

HELVETICA CHIMICA ACTA, 1954, 37 (01) :383-388

[6] INFRARED SPECTRA OF ARYL AZIDES [J].

DYALL, LK ;

KEMP, JE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1967, 20 (07) :1395-&

[7]

FONES WS, 1949, ARCH BIOCHEM, V20, P118

[8] Determination of 15N nitrate and nitrite in spiked natural waters [J].

Kieber, RJ ;

Bullard, L ;

Seaton, PJ .

ANALYTICAL CHEMISTRY, 1998, 70 (18) :3969-3973

[9] RECENT TRENDS IN PHOTOAFFINITY-LABELING [J].

KOTZYBAHIBERT, F ;

KAPFER, I ;

GOELDNER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (12) :1296-1312

[10]

LIEVER E, 1959, J ORG CHEM, V24, P1014

← 1 2 →