Photo-Initiated Dispersion Polymerization of Copolymer Microspheres in a Closed System: Poly(MMA-co-MAA)

被引：14

作者：

Huang, Zhenxun ^{[1
]}

Sun, Fengqiang ^{[1
,2
,3
]}

Liang, Shangheng ^{[1
]}

Wang, Hongjuan ^{[1
]}

Shi, Guang ^{[1
]}

Tao, Lijun ^{[1
]}

Tan, Jianxiong ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

[2] GuangDong Univ, Key Lab Electrochem Technol Energy Storage & Powe, Guangzhou 510006, Guangdong, Peoples R China

[3] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2010年 / 211卷 / 17期

基金：

中国国家自然科学基金;

关键词：

AIBN; copolymerization; copolymer microspheres; dispersion polymerization; photopolymerization; MONODISPERSE POLYSTYRENE MICROSPHERES; PARTICLES; SIZE; SPHERES; GROWTH; ARRAYS; NARROW;

D O I：

10.1002/macp.201000023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A simple closed system is introduced to construct copolymer microspheres with specific surface groups by low-power UV irradiation. As an example, poly(MMA-co-MAA) microspheres with narrow size distribution were prepared by photo-initiated dispersion polymerization. Sizes and size distributions of the microspheres were closely related to light intensity, composition of dispersion medium and the concentrations of initiators, stabilizers, and monomers. Many carboxyl groups could be moored on the spheres' surfaces, which enabled the construction of nanostructures on the surface. Many copolymer microspheres with different surface functional groups, such as -NH2, -SH, -OH, etc. could be directly prepared in an ordinary laboratory.

引用

页码：1868 / 1878

页数：11

共 28 条

[1] Controlled selective growth of ZnO nanorod arrays and their field emission properties [J].

Ahsanulhaq, Q. ;

Kim, Jin-Hwan ;

Hahn, Yoon-Bong .

NANOTECHNOLOGY, 2007, 18 (48)

[2] Synthesis of narrow or monodisperse poly(divinylbenzene) microspheres by distillation-precipitation polymerization [J].

Bai, F ;

Yang, XL ;

Huang, WQ .

MACROMOLECULES, 2004, 37 (26) :9746-9752

[3] Photoinitiated dispersion polymerization of methyl methacrylate: A quick approach to prepare polymer microspheres with narrow size distribution [J].

Chen, Jia ;

Zeng, Zhaohua ;

Yang, Jiianwen ;

Chen, Yonglie .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (04) :1329-1338

[4] Amorphous Ni-B hollow spheres synthesized by controlled organization of Ni-B nanoparticles over PS beads via surface seeding/electroless plating [J].

Chen, XY ;

Yang, WL ;

Wang, S ;

Qiao, MH ;

Yan, SR ;

Fan, KN ;

He, HY .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (02) :266-268

[5] Preparation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization using vinyl terminus polysiloxane macromonomer as a polymerizable stabilizer [J].

Dai, Q ;

Wu, DZ ;

Zhang, ZC ;

Ye, Q .

POLYMER, 2003, 44 (01) :73-77

[6] Preparation of monodisperse polymer particles by photopolymerization [J].

Esen, C ;

Schweiger, G .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 179 (01) :276-280

[7] Synthesis of epoxy-functional microspheres by cationic suspension photopolymerization [J].

Falk, B ;

Crivello, JV .

CHEMISTRY OF MATERIALS, 2004, 16 (24) :5033-5041

[8] Template-induced directional growth of ZnO nanomeshes by colloidal crystals [J].

Fu, Ming ;

Zhou, Ji ;

Li, Bo ;

Huang, Xueguang ;

Wang, Yuehui ;

Li, Longtu .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (48) :5986-5992

[9] Synthesis of monodisperse polymer microspheres by photopolymerization of microdroplets [J].

Gao, Zhiqiang ;

Grulke, Eric A. ;

Ray, Asit K. .

COLLOID AND POLYMER SCIENCE, 2007, 285 (08) :847-854

[10] Synthesis of PS/PMMA core-shell structured particles by seeded suspension polymerization [J].

Goncalves, Odinei H. ;

Asua, Jose M. ;

Hermes de Araujo, Pedro Henrique ;

Machado, Ricardo A. F. .

MACROMOLECULES, 2008, 41 (19) :6960-6964

← 1 2 3 →