The thermal stability of cross-linked polymers: methyl methacrylate with divinylbenzene and styrene with dimethacrylates

被引：74
作者：
Uhl, FM
Levchik, GF
Levchik, SV
Dick, C
Liggat, JJ
Snape, CE
Wilkie, CA
机构：
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
[2] Belarusian State Univ, Phys Chem Problems Res Inst, Minsk 220050, BELARUS
[3] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
来源：
POLYMER DEGRADATION AND STABILITY | 2001年 / 71卷 / 02期
关键词：
thermal stability; cross-linking; methyl methacrylate; styrene; divinylbenzene; dimethacrylates;
D O I：
10.1016/S0141-3910(00)00181-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Cross-linking of polymers is frequently presumed to enhance the thermal stability of polymer systems. Methyl methacrylate has been reacted with divinylbenzene and styrene with various dimethacrylates. These systems have been characterized by gel content, swelling ratio, infrared spectroscopy, thermal analysis, TGA/FT-IR, and solid state NMR. Both systems show enhanced thermal stability and char formation. This is most pronounced in the cases of methyl methacrylate with divinylbenzene and styrene with bisphenol A dimethacrylate. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：317 / 325
页数：9
相关论文
共 18 条
[1]  
BALABANOVICH AI, 1998, FIRE RETARDANCY POLY, P236
[2]  
BOVEY FA, 1996, NMR POLYM, P255
[3]  
BYWATER S, 1954, J PHYS CHEM-US, V57, P879
[4]  
Conley R T, 1966, INFRARED SPECTROSCOP, P87
[5]   Statistical mechanics of cross-linked polymer networks II Swelling [J].
Flory, PJ ;
Rehner, J .
JOURNAL OF CHEMICAL PHYSICS, 1943, 11 (11) :521-526
[6]   Statistical mechanics of cross-linked polymer networks I Rubberlike elasticity [J].
Flory, PJ ;
Rehner, J .
JOURNAL OF CHEMICAL PHYSICS, 1943, 11 (11) :512-520
[7]   THE THERMAL DEGRADATION OF POLYVINYL COMPOUNDS .4. THE THERMAL DEGRADATION OF THE METHYL METHACRYLATE COPOLYMERS WITH GLYCOL DIMETHACRYLATE AND ACRYLONITRILE [J].
GRASSIE, N ;
MELVILLE, HW .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1949, 199 (1056) :39-55
[8]  
Grassie N, 1985, POLYM DEGRADATION ST, P23
[9]   TECHNIQUES FOR THE ANALYSIS OF CROSSLINKED POLYMERS [J].
HARRISON, DJP ;
YATES, WR .
JOURNAL OF MACROMOLECULAR SCIENCE-REVIEWS IN MACROMOLECULAR CHEMISTRY AND PHYSICS, 1985, C25 (04) :481-549
[10]   Thermal decomposition of cross-linked polybutadiene and its copolymers [J].
Jiang, DD ;
Levchik, GF ;
Levchik, SV ;
Wilkie, CA .
POLYMER DEGRADATION AND STABILITY, 1999, 65 (03) :387-394
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