Synthesis and catalytic properties of 1-alkylperimidineruthenium (II) complexes

被引：17
作者：
Alici, B
Özdemir, I
Karaaslan, K
Çetinkaya, E
Çetinkaya, B
机构：
[1] Inonu Univ, Fac Sci & Arts, Dept Chem, Malatya 44069, Turkey
[2] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2005年 / 231卷 / 1-2期
关键词：
perimidine; olefin isomerization; ruthenium complexes; cycloisomerization;
D O I：
10.1016/j.molcata.2004.12.036
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Four new [RuCl2(perimidine)(p-cymene)] complexes have been prepared and characterized. Upon reaction with 1,1-diphenylprop-2-yn-1-ol they generate catalyst precursors. which perform the cycloisomerization of diallyltosylamide into N-tosyl-alpha-methylenepyrrolidine. (c) 2005 Elsevier B.V. All rights reserved.
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收藏
页码：261 / 264
页数：4
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