Cross-Coupling of Mesylated Phenol Derivatives with Potassium Ammonio- and Amidomethyltrifluoroborates

被引：34

作者：

Molander, Gary A. ^{[1
]}

Beaumard, Floriane ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana A Vagelos Labs, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 05期

关键词：

GENERAL PALLADIUM CATALYST; SUZUKI-MIYAURA; ARYL TOSYLATES; REDUCTIVE AMINATION; ARENESULFONATES; HALIDES; KETONES; AMINOMETHYLATIONS; ALDEHYDES; NITRILES;

D O I：

10.1021/ol200128y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A large array of aryl and heteroaryl mesylates have been successfully employed as electrophiles in a Csp(2)-Csp(3) Suzuki-Miyaura cross-coupling with potassium ammonio- and amidomethyltrifluoroborates to afford the corresponding products in high yields.

引用

页码：1242 / 1245

页数：4

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