Bifunctional fluorescent thiacalix[4]arene based chemosensor for Cu2+ and F- ions

被引：81

作者：

Bhalla, Vandana ^{[1
]}

Kumar, Rajesh ^{[1
]}

Kumar, Manoj ^{[1
]}

Dhir, Abhimanew ^{[1
]}

机构：

[1] Guru Nanak Dev Univ, Dept Chem, Amritsar 143005, Punjab, India

来源：

TETRAHEDRON | 2007年 / 63卷 / 45期

关键词：

thaicalix[4]arene; ratiometric sensing; fluorescent Cu2+ sensor;

D O I：

10.1016/j.tet.2007.08.021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new thiacalix[4]arene based fluorescent sensor bearing two dansyl groups has been synthesized in cone conformation. In CH3CN:CH2Cl2(1:1), the presence of Cu (II) induces the formation of a 1:1 metal: ligand complex, which exhibits increasing emission at 433 nm at the expense of the fluorescent emission of 1 centered at 504 nm. The detection limit of the sensor for Cu2+ is 2 x 10(-7) mol L-1. For anion sensing, 1 shows a high selectivity for fluoride ions over other anions tested. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：11153 / 11159

页数：7

共 109 条

[1] Chiral receptors for phosphate ions [J].

Amendola, V ;

Boiocchi, M ;

Esteban-Gómez, D ;

Fabbrizzi, L ;

Monzani, E .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (14) :2632-2639

[2] Calix[4]pyrroles containing deep cavities and fixed walls.: Synthesis, structural studies, and anion binding properties of the isomeric products derived from the condensation of p-hydroxyacetophenone and pyrrole [J].

Anzenbacher, P ;

Jursíková, K ;

Lynch, VM ;

Gale, PA ;

Sessler, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (47) :11020-11021

[3] New "cholapod" anionophores; high-affinity halide receptors derived from cholic acid [J].

Ayling, AJ ;

Pérez-Payán, MN ;

Davis, AP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (50) :12716-12717

[4] Recent developments in transition metal ion detection by luminescent chemosensors [J].

Bargossi, C ;

Fiorini, MC ;

Montalti, M ;

Prodi, L ;

Zaccheroni, N .

COORDINATION CHEMISTRY REVIEWS, 2000, 208 :17-32

[5] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[6] Synthesis and binding studies of novel bisthiacalix[4]arenes with diimime linkages [J].

Bhalla, V ;

Kumar, M ;

Katagiri, H ;

Hattori, T ;

Miyano, S .

TETRAHEDRON LETTERS, 2005, 46 (01) :121-124

[7] Stereoselective synthesis of all stereoisomers of vicinal and distal bis(O-2-aminoethyl)-p-tert-butylthiacalix[4]arene [J].

Bhalla, V ;

Kumar, M ;

Hattori, T ;

Miyano, S .

TETRAHEDRON, 2004, 60 (28) :5881-5887

[8] Synthesis and binding studies of novel thiacalixpodands and bisthiacalixarenes having O,O"-dialkylated thiacalix[4]arene unit(s) of 1,3-alternate conformation [J].

Bhalla, Vandana ;

Babu, J. Nagendra ;

Kumar, Manoj ;

Hattori, Tetsutaro ;

Miyano, Sotaro .

TETRAHEDRON LETTERS, 2007, 48 (09) :1581-1585

[9] Anion-induced urea deprotonation [J].

Boiocchi, M ;

Del Boca, L ;

Esteban-Gómez, D ;

Fabbrizzi, L ;

Licchelli, M ;

Monzani, E .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (10) :3097-3104

[10] A two-channel molecular dosimeter for the optical detection of copper(II) [J].

Boiocchi, M ;

Fabbrizzi, L ;

Licchelli, M ;

Sacchi, D ;

Vázquez, M ;

Zampa, C .

CHEMICAL COMMUNICATIONS, 2003, (15) :1812-1813

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