Study on volumetric measurement and correlations for MTBE+1-propanol+decane at 298.15 K and atmospheric pressure

被引:9
作者
Mato, MM
Cebreiro, SM
Verdes, PV
Pallas, AV
Legido, JL
Andrade, MIP
机构
[1] Univ Santiago de Compostela, Fac Fis, Dept Fis Aplicada, Santiago De Compostela 15782, Spain
[2] Univ Vigo, Fac Ciencias, Dept Fis Aplicada, Vigo 36200, Spain
关键词
binary mixtures; ternary mixture; excess molar volumes; empirical expressions; 1-propanol; tert-butyl methyl ether (MTBE); decane;
D O I
10.1007/s10973-005-0653-2
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental densities for the ternary mixture x(1)MTBE+x(2)1-propanol+(1-x(1)-x(2))decane and the binary mixtures xMTBE +(1-x)1-propanol and x1-propanol+(1-x)decane have been measured at 298.15 K and atmospheric pressure, using a DMA 4500 Anton Paar densimeter. Excess molar volumes were determined from the densities of the pure liquids and mixtures. Attending to the symmetry of the studied mixtures, suitable fitting equations have been used in order to correlate adequately the experimental data. For the ternary mixture, experimental data were also used to test several empirical expressions for estimating ternary properties from experimental binary results.
引用
收藏
页码:317 / 321
页数:5
相关论文
共 21 条
[1]  
Bevington R., 1969, DATA REDUCTION ERROR
[2]   THERMODYNAMIC EXCESS FUNCTIONS OF BINARY SOLUTIONS INVOLVING A FLUOROALCOHOL [J].
BRANDRETH, DA ;
ONEILL, SP ;
MISSEN, RW .
TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (525P) :2355-+
[3]  
Colinet C, 1967, THESIS U GRENOBLE FR
[4]  
CRC, 2003, HDB CHEM PHYS
[5]   EMPIRICAL-METHODS OF PREDICTING AND REPRESENTING THERMODYNAMIC PROPERTIES OF TERNARY SOLUTION PHASES [J].
HILLERT, M .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1980, 4 (01) :1-12
[6]   ESTIMATION OF THERMODYNAMIC PROPERTIES OF TERNARY ALLOYS FROM BINARY DATA USING SHORTEST DISTANCE COMPOSITION PATH [J].
JACOB, KT ;
FITZNER, K .
THERMOCHIMICA ACTA, 1977, 18 (02) :197-206
[7]  
Knobeloch J. B., 1962, J CHEM ENG DATA, V7, P386
[8]  
Kohler F., 1960, Monatsh. Chem, V91, P738, DOI [10.1007/BF00899814, 10.1007/bf00899814, DOI 10.1007/BF00899814]
[9]   THERMODYNAMIC PROPERTIES OF BINARY-MIXTURES OF 2-HEXANONE WITH NORMAL-ALKANES AT 35-DEGREES-C [J].
LEGIDO, JL ;
LORENZANA, MT ;
JIMENEZ, E ;
FERNANDEZ, J ;
AMIGO, A ;
ANDRADE, MIP .
JOURNAL OF SOLUTION CHEMISTRY, 1990, 19 (11) :1095-1102
[10]   THERMODYNAMIC PROPERTIES OF (A PROPYL ESTER + AN N-ALKANE) AT 298.15K .1. [XC2H5CO2C3H7 + (1-X)C6-TO-10H2(6-TO-10)+2] [J].
LORENZANA, MT ;
LEGIDO, JL ;
JIMENEZ, E ;
FERNANDEZ, J ;
PIAS, L ;
ORTEGA, J ;
ANDRADE, MIP .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1989, 21 (10) :1017-1022