Knowledge of the temperature dependence of the material properties of tissue-mimicking materials is useful or essential for many applications. This includes photoacoustic thermometry where the temperature dependence of the Gruneisen parameter of tissues leads to changes in the recorded photoacoustic signal amplitude with temperature. Here, a setup is described that can measure the temperature dependence of the speed of sound and photoacoustic conversion efficiency (mu(a)Gamma) of tissue-mimicking materials. Agar-based phantoms, copolymer-in-oil, gel wax, PVCP, silicone and water were characterised in the newly developed setup for temperatures between 22 degrees C and 50 degrees C. This information provides a valuable resource for material characterisation and future development of tissue-mimicking materials.