Highly efficient controllable oxidation of alcohols to aldehydes and acids with sodium periodate catalyzed by water-soluble metalloporphyrins as biomimetic catalyst

被引：41

作者：

Ren, Qing-Gang ^{[1
]}

Chen, Shao-Yun ^{[1
]}

Zhou, Xian-Tai ^{[1
]}

Ji, Hong-Bing ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Key Lab Low Carbon Chem & Energy Conservat Guangd, Guangzhou 510275, Guangdong, Peoples R China

来源：

BIOORGANIC & MEDICINAL CHEMISTRY | 2010年 / 18卷 / 23期

基金：

中国国家自然科学基金;

关键词：

Water-soluble metalloporphyrins; Controllable oxidation; Alcohols; Aldehydes; MESO-TETRAPHENYLPORPHYRIN CHLORIDE; MOLECULAR-OXYGEN; SELECTIVE OXIDATION; PORPHYRINS; MECHANISM; SULFIDES; KINETICS; LIQUID;

D O I：

10.1016/j.bmc.2010.10.026

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Highly efficient controllable oxidation of alcohols to aldehydes or acids by sodium periodate in the presence of water-soluble manganese porphyrins (meso-tetrakis(N-ethylpyridinium-4-yl) manganese porphyrin, MnTEPyP) with different reaction media has been reported. The manganese porphyrin showed excellent activity for the controllable oxidation of various alcohols under mild conditions. Moreover, different factors influencing alcohol oxidation, for example, oxidant, catalyst amount, temperature, and solvent, have been investigated. A plausible mechanism for the controllable oxidation of alcohol has been proposed. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：8144 / 8149

页数：6

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