A lacuna in reticular chemistry: an unprecedented binodal (6,10)-connected network based on two distinct zinc clusters

被引:34
作者
Qin, Jie [1 ]
Qin, Chao [1 ]
Wang, Cui-Xia [1 ]
Li, Huan [1 ]
Cui, Ling [1 ]
Li, Ting-Ting [1 ]
Wang, Xin-Long [1 ]
机构
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalates Sci, Changchun 130024, Peoples R China
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; DESIGN; NETS;
D O I
10.1039/c0ce00582g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first binodal (6,10)-connected metal-organic network, based on an octahedral binuclear zinc cluster as a six-connected node and a dodecahedral pentanuclear zinc cluster as a ten-connected node, defines a new topology for three-periodic nets that is not only unobserved in crystal structures, but also unenumerated in electronic topological databases.
引用
收藏
页码:4071 / 4073
页数:3
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