Self-assembly of nanometre-scale metallacalix[4]arene building blocks and Keggin units to a novel (3,4)-connected 3D self-penetrating framework

被引：127

作者：

Wang, Xiuli ^{[1
]}

Hu, Hailiang ^{[1
]}

Liu, Guocheng ^{[1
]}

Lin, Hongyan ^{[1
]}

Tian, Aixiang ^{[1
]}

机构：

[1] Bohai Univ, Fac Chem & Chem Engn, Jinzhou 121000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 35期

基金：

中国国家自然科学基金;

关键词：

HYDROTHERMAL CONDITIONS; COORDINATION POLYMERS; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; CLUSTERS; ARCHITECTURES; CHANNELS; LIGAND; DIMER;

D O I：

10.1039/c0cc01412e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel (3,4)-connected 3D self-penetrating metal-organic framework with a nanometre-scale cavity constructed from metallacalix[4]arene building blocks and Keggin-type polyanions has been obtained by using a 1,3-bis(1-methyl-5-mercapto-1,2,3,4-tetrazole)propane ligand.

引用

页码：6485 / 6487

页数：3

共 33 条

[1] Chiral 3D architectures with helical channels constructed from polyoxometalate clusters and copper-amino acid complexes [J].

An, HY ;

Wang, EB ;

Xiao, DR ;

Li, YG ;

Su, ZM ;

Xu, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :904-908

[2] OLEX:: new software for visualization and analysis of extended crystal structures [J].

Dolomanov, OV ;

Blake, AJ ;

Champness, NR ;

Schröder, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1283-1284

[3] Crystal Structures and Properties of Large Protonated Water Clusters Encapsulated by Metal-Organic Frameworks [J].

Duan, Chunying ;

Wei, Meilin ;

Guo, Dong ;

He, Cheng ;

Meng, Qingjin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (10) :3321-3330

[4] Constructing Robust Channel Structures by Packing Metallacalixarenes: Reversible Single-Crystal-to-Single-Crystal Dehydration [J].

Ene, Cristian D. ;

Madalan, Augustin M. ;

Maxim, Catalin ;

Jurca, Bogdan ;

Avarvari, Narcis ;

Andruh, Marius .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) :4586-+

[5] Efficient epoxidation of olefins with ≥ 99% selectivity and use of hydrogen peroxide [J].

Kamata, K ;

Yonehara, K ;

Sumida, Y ;

Yamaguchi, K ;

Hikichi, S ;

Mizuno, N .

SCIENCE, 2003, 300 (5621) :964-966

[6]

KEEFFE MO, 1996, CRYSTAL STRUCTURES

[7] Construction of polyoxometalates-based coordination polymers through direct incorporation between polyoxometalates and the voids in a 2D network [J].

Kong, Xiang-Jian ;

Ren, Yan-Ping ;

Zheng, Pei-Qing ;

Long, Yu-Xiang ;

Long, La-Sheng ;

Huang, Rong-Bin ;

Zheng, Lan-Sun .

INORGANIC CHEMISTRY, 2006, 45 (26) :10702-10711

[8]

Kozhevnikov I.V., 2002, Catalysts for fine chemical synthesis, Catalysis by polyoxometalates, V2

[9] Dioxygen and Water Activation Processes on Multi-Ru-Substituted Polyoxometalates: Comparison with the "Blue-Dimer" Water Oxidation Catalyst [J].

Kuznetsov, Aleksey E. ;

Geletii, Yurii V. ;

Hill, Craig L. ;

Morokuma, Keiji ;

Musaev, Djamaladdin G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (19) :6844-6854

[10] Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand [J].

Lan, Ya-Qian ;

Li, Shun-Li ;

Su, Zhong-Min ;

Shao, Kui-Zhan ;

Ma, Jian-Fang ;

Wang, Xin-Long ;

Wang, En-Bo .

CHEMICAL COMMUNICATIONS, 2008, (01) :58-60

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