A hierarchically core/shell-structured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes

被引：35

作者：

Li, Chen-Geng ^{[1
]}

Lu, Yiqun ^{[1
]}

Wu, Haihong ^{[1
]}

Wu, Peng ^{[1
]}

He, Mingyuan ^{[1
]}

机构：

[1] E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 80期

关键词：

UNIT-CELL THICKNESS; CATALYTIC-PROPERTIES; HYDROGEN-PEROXIDE; TI-MWW; ZEOLITES; MFI; HYDROXYLATION; SILICALITE; NANOSHEETS; PHENOL;

D O I：

10.1039/c5cc05278e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hierarchical titanosilicate, with epitaxially grown MFI nanosheets on microsized TS-1 crystals, has been prepared through a desilication-recrystallization method using a diammonium surfactant as the secondary structure-directing agent (SDA). This core/shell material features multiple mesoporosities, significantly improved epoxidation activity as well as easy separation in synthesis and catalytic reactions.

引用

页码：14905 / 14908

页数：4

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