Novel promoting effects of tungsten on the selective catalytic reduction of NO by NH3 over MnOx-CeO2 monolith catalyst

被引:34
作者
Zhang, Qiulin [1 ]
Qiu, Chuntian [1 ]
Xu, Haidi [1 ]
Lin, Tao [1 ]
Gong, Maochu [1 ]
Chen, Yaoqiang [1 ]
机构
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
基金
中国国家自然科学基金;
关键词
Selective catalytic reduction; Tungsten modified MnO(x)-CeO(2); Monolith catalyst; NO reduction; LOW-TEMPERATURE SCR; V2O5-WO3/TIO2; CATALYSTS; SUPERIOR CATALYST; OXIDE CATALYSTS; PERFORMANCE; DURABILITY; OXIDATION; AMMONIA;
D O I
10.1016/j.catcom.2011.08.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of tungsten modified MnO(x)-CeO(2) monolith catalysts were prepared and used for selective catalytic reduction (SCR) of NO by NH(3) in the presence of O(2). The experimental results showed that the SCR performance and SO(2)-resistant ability of MnO(x)-CeO(2) were greatly enhanced by the introduction of tungsten. The catalyst containing 10% WO(3) showed the highest NO conversion in a wide temperature range of 162-374 degrees C. The highly dispersed or amorphous tungsten oxide and the strong interaction between tungsten and MnO(x)-CeO(2) should be the reasons for the excellent performance of the catalyst containing 10% WO(3). (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:20 / 24
页数:5
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