Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture

被引：30

作者：

Gigmes, Didier ^{[1
]}

Dufils, Pierre-Emmanuel

Gle, David

Bertin, Denis

Lefay, Catherine

Guillaneuf, Yohann

机构：

[1] Univ Aix Marseille 1, Lab Chim Provence, Equipe CROPS, UMR 6264, F-13397 Marseille 20, France

来源：

POLYMER CHEMISTRY | 2011年 / 2卷 / 08期

关键词：

FRAGMENTATION CHAIN TRANSFER; NITROXIDE-MEDIATED POLYMERIZATION; BLOCK-COPOLYMERS; TRIBLOCK COPOLYMERS; RAFT PROCESS; COPPER-COMPLEXES; SIZE; POLYETHYLENE; METAL; CHEMISTRY;

D O I：

10.1039/c1py00057h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This review described the potential of the intermolecular radical 1,2-addition from the commercially available BlocBuilder MA alkoxyamine onto activated olefins to synthesize either new functionalized alkoxyamines or various macromolecular architectures. Following this approach, diblock, triblock copolymers, star polymers and hybrid materials are then easily prepared. The various applications of such architectures will be briefly reviewed. Interestingly this new synthetic tool widely expands the range of complex macromolecular architectures which could be obtained by the nitroxide-mediated polymerization (NMP) process.

引用

页码：1624 / 1631

页数：8

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