Recent Advances in Luminescent Hydrogen-Bonded Organic Frameworks: Structures, Photophysical Properties, Applications

被引:87
作者
Cai, Suzhi [1 ,2 ]
An, Zhongfu [3 ,4 ]
Huang, Wei [1 ,2 ,3 ,4 ,5 ]
机构
[1] Fujian Normal Univ, Strait Inst Flexible Elect SIFE, Future Technol, Fuzhou 350117, Fujian, Peoples R China
[2] Strait Lab Flexible Elect SLoFE, Fuzhou 350117, Fujian, Peoples R China
[3] Nanjing Tech Univ, Key Lab Flexible Elect, Nanjing 211816, Peoples R China
[4] Nanjing Tech Univ, Inst Adv Mat, Nanjing 211816, Peoples R China
[5] Northwestern Polytech Univ, Frontiers Sci Ctr Flexible Elect, Shaanxi Inst Flexible Elect SIFE, 127 West Youyi Rd, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
chemical sensors; fluorescence; hydrogen-bonded organic frameworks; room temperature phosphorescence; stimuli-responsiveness; INDUCED PHOSPHORESCENCE; DESIGN; CONFORMATION; HOF;
D O I
10.1002/adfm.202207145
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogen-bonded organic frameworks (HOFs) have aroused interest due to their applications in gas storage and separation and proton conduction. Much effort has been focused on developing stable HOFs with permanent porosity. Recently, more attention has been paid to the development of luminescent HOFs. At present, a systematic study on luminescent HOFs is lacking. Here, recent advances in luminescent HOFs are highlighted. The construction of luminescent HOFs, luminescent properties of HOFs, and corresponding applications are discussed in detail. According to luminescent properties, luminescent HOFs can be divided into fluorescent HOFs and room-temperature phosphorescent HOFs. In addition, HOFs with color-tunable luminescence, stimuli-responsive luminescence, or mechanoluminescence are also introduced at great length. These distinctive features endow HOFs with wide applications in chemical sensing, microlasers, stimuli-responsive sensing, oxygen sensing, data encryption, and so on. This review not only provides the basic principle of designing luminescent HOFs but also points out the research perspectives of luminescent HOFs in the future. This review lays the foundation for developing luminescent HOFs, thus broadening the applications of HOFs and enriching luminescent porous materials.
引用
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页数:19
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