Polymer-Immobilized Clusters and Metal Nanoparticles in Catalysis

被引：39

作者：

Dzhardimalieva, G. I. ^{[1
]}

Zharmagambetova, A. K. ^{[2
]}

Kudaibergenov, S. E. ^{[3
,4
]}

Uflyand, I. E. ^{[5
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia

[2] Sokolskii Inst Organ Catalysis & Electrochem, Alma Ata 050010, Kazakhstan

[3] Inst Polymer Mat & Technol, Alma Ata 050019, Kazakhstan

[4] Satbaev Univ, Lab Engn Profile, Alma Ata 050013, Kazakhstan

[5] South Fed Univ, Rostov Na Donu 344006, Russia

来源：

KINETICS AND CATALYSIS | 2020年 / 61卷 / 02期

关键词：

metal nanoparticles; cluster-containing polymers; catalysis; polymer matrix; macroporous gels; polymer-immobilized catalysts; CROSS-COUPLING REACTIONS; MACROPOROUS AMPHOTERIC CRYOGELS; HIGHLY-ACTIVE HYDROGENATION; CO-MALEIC ACID); PALLADIUM NANOPARTICLES; IONIC LIQUID; GOLD NANOPARTICLES; PD NANOPARTICLES; H-2; PRODUCTION; ALPHA; BETA-UNSATURATED ALDEHYDES;

D O I：

10.1134/S0023158420020044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recent advances in the synthesis of polymer-immobilized clusters and metal nanoparticles and their use in catalysis of many organic reactions were presented. The main types of polymer-immobilized catalysts were considered, including cluster-containing polymers, polymer-protected metal nanoparticles fixed on inorganic supports, and gel-immobilized catalysts. Special attention was paid to the role of the polymer matrix. It functions not only as a stabilizing agent that prevents the aggregation of nanoparticles and their leaching into the reaction medium, but also as a ligand in the coordination sphere of the metal site, which allows the advantages of homogeneous and heterogeneous catalysts to be combined in one catalyst.

引用

页码：198 / 223

页数：26

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