Highly Efficient and Chemoselective Hydrogenation of Nitro Compounds into Amines by Nitrogen-Doped Porous Carbon-Supported Co/Ni Bimetallic Nanoparticles

被引：17

作者：

Shen, Zeyu ^{[1
]}

Hong, Lirui ^{[2
]}

Zheng, Baishu ^{[1
]}

Wang, Guanyu ^{[1
]}

Zhang, Beibei ^{[2
]}

Wang, Zhaoxu ^{[1
]}

Zhan, Feiyang ^{[2
]}

Shen, Shaohua ^{[1
]}

Yun, Ruirui ^{[2
]}

机构：

[1] Hunan Univ Sci & Technol, Key Lab Theoret Organ Chem & Funct Mol, Hunan Prov Key Lab Controllable Preparat & Funct, Sch Chem & Chem Engn,Minist Educ, Xiangtan 411201, Peoples R China

[2] Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Wuhu 241000, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 21期

关键词：

SELECTIVE HYDROGENATION; CATALYST; NITROARENES; REDUCTION;

D O I：

10.1021/acs.inorgchem.1c02740

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel Co/Ni bimetallic nanoparticle supported by nitrogen- doped porous carbon (NPC), Co-5/Ni@NPC-700, exhibits high conversion, chemoselectivity, and recyclability in the hydrogenation of 16 different nitro compounds into desired amines with hydrazine hydrate under mild conditions. The synergistic effects of Co/Ni bimetal nanoparticles and the NPC-supported porous honeycomb structure with more accessible active sites may be responsible for the high catalytic hydrogenation performance.

引用

页码：16834 / 16839

页数：6

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