Preparation of 2-phospholene derivatives from zirconacyclopentenes

被引：10

作者：

Zhou, Yiging ^{[1
]}

Yan, Xiaoyu ^{[1
]}

Xi, Chanjuan ^{[1
,2
]}

机构：

[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China

[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 47期

基金：

中国国家自然科学基金;

关键词：

Zirconacyclopentenes; Dichlorophosphine; Phospholene; Heterocycles; MOLECULAR-COMPLEX FORMATION; METALLACYCLE TRANSFER; TADDOL DERIVATIVES; PHOSPHOLENE OXIDES; CONVENIENT METHOD; P-HETEROCYCLES; LIGANDS; 1-OXIDES; HYDROFORMYLATION; RESOLUTION;

D O I：

10.1016/j.tetlet.2010.09.061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zirconacyclopentenes, which are easily prepared from alkynes, alkenes, and zirconocene compounds, reacted with dichlorophenylphosphine to give 2-phospholene in high yields. The reaction was performed conveniently in one-pot from an alkyne, alkene, dichlorophosphine, and zirconocene compounds. (C) 2010 Elsevier Ltd. All rights reserved.

引用

收藏

页码：6136 / 6138

页数：3

相关论文

共 29 条

[1] Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium(I) hydroformylation catalysts [J].

Baber, RA ;

Clarke, ML ;

Heslop, KM ;

Marr, AC ;

Orpen, AG ;

Pringle, PG ;

Ward, A ;

Zambrano-Williams, DE .

DALTON TRANSACTIONS, 2005, (06) :1079-1085

[2] Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes [J].

Breit, B ;

Fuchs, E .

CHEMICAL COMMUNICATIONS, 2004, (06) :694-695

[3] Recent developments in chiral phospholane chemistry [J].

Clark, TP ;

Landis, CR .

TETRAHEDRON-ASYMMETRY, 2004, 15 (14) :2123-2137

[4] EQUILIBRIUM BETWEEN METALLAINDANS AND ARYNE OLEFIN-METAL COMPLEXES [J].

ERKER, G ;

KROPP, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (13) :3659-3660

[5] METALLACYCLE TRANSFER FROM ZIRCONIUM TO MAIN-GROUP ELEMENTS - A VERSATILE SYNTHESIS OF HETEROCYCLES [J].

FAGAN, PJ ;

NUGENT, WA ;

CALABRESE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) :1880-1889

[6] SYNTHESIS OF MAIN GROUP HETEROCYCLES BY METALLACYCLE TRANSFER FROM ZIRCONIUM [J].

FAGAN, PJ ;

NUGENT, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2310-2312

[7] Synthesis of the spiro derivatives of 1,2-oxaphosphetes by [2+2] cycloaddition of cyclic 1-(2,4,6-triisopropylphenyl)phosphine oxides with dimethyl acetylenedicarboxylate [J].

Keglevich, G ;

Forintos, H ;

Keserü, GM ;

Hegedüs, L ;

Töke, L .

TETRAHEDRON, 2000, 56 (27) :4823-4828

[8] Ligands for practical rhodium-catalyzed asymmetric hydroformylation [J].

Klosin, Jerzy ;

Landis, Clark R. .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (12) :1251-1259

[9] P-Heterocycles as Ligands in Homogeneous Catalytic Reactions [J].

Kollar, L. ;

Keglevich, G. .

CHEMICAL REVIEWS, 2010, 110 (07) :4257-4302

[10] New 7-phosphanorbornenes derived from 2-methyl-1-phenyl- and 1-cyclohexyl-3-methyl-2,5-dihydro-1H-phosphole 1-oxides [J].

Kovács, J ;

Szabó, NB ;

Nagy, Z ;

Ludányi, K ;

Keglevich, G .

HETEROATOM CHEMISTRY, 2005, 16 (05) :320-326