Bis(dipyrrinato)zinc(II) Complexes: Emission in the Solid State

被引:39
作者
Tsuchiya, Mizuho [1 ]
Sakamoto, Ryota [1 ,2 ]
Shimada, Masaki [1 ]
Yamanoi, Yoshinori [1 ]
Hattori, Yohei [1 ]
Sugimoto, Kunihisa [3 ]
Nishibori, Eiji [4 ,5 ]
Nishihara, Hiroshi [1 ]
机构
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan
[2] JST PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan
[3] Japan Synchrotron Radiat Res Inst JASRI, 1-1-1 Koto, Sayo, Hyogo 6795198, Japan
[4] Univ Tsukuba, Fac Pure & Appl Sci, Tsukuba Res Ctr Interdisciplinary Mat Sci, Div Phys, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan
[5] Univ Tsukuba, Ctr Integrated Res Fundamental Sci & Engn, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan
关键词
STRUCTURAL CONTROL; BODIPY DYES; CHEMISTRY;
D O I
10.1021/acs.inorgchem.6b00431
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This Communication reports the first observation of solid-state photoluminescence in bis(dipyrrinato)zinc(II) complexes with various substituents. The report discusses the effect of their substituents on their crystal structures and spectroscopic properties. Their meso-aryl groups are revealed to play important roles in the spectroscopic properties in the solid state.
引用
收藏
页码:5732 / 5734
页数:3
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