NaSr3Be3B3O9F4: A Promising Deep-Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10- Anionic Group

被引：336

作者：

Huang, Hongwei ^{[1
]}

Yao, Jiyong ^{[1
]}

Lin, Zheshuai ^{[1
]}

Wang, Xiaoyang ^{[1
]}

He, Ran ^{[1
]}

Yao, Wenjiao ^{[1
]}

Zhai, Naixia ^{[1
]}

Chen, Chuangtian ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 39期

基金：

中国国家自然科学基金;

关键词：

borates; electronic structure; nonlinear optics; solid-state structures; structure-property relationships; STRONG 2ND-HARMONIC GENERATION; UV ABSORPTION; CRYSTALS; BORATE; PSEUDOPOTENTIALS; MODEL; EDGE; RB;

D O I：

10.1002/anie.201103960

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structure matters: Owing to the structure and arrangement of the [Be 3B3O12F]10- group (see picture, left, Be blue, B olive, F green, O red), the mixed-cation fluorine beryllium borate NaSr3Be3B3O9F4 (right) exhibits a large second harmonic generation effect and a short UV absorption edge. Its crystals show no layering tendency, making it promising for applications in deep-UV nonlinear optics. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9141 / 9144

页数：4

共 39 条

[31] SPECIAL POINTS FOR BRILLOUIN-ZONE INTEGRATIONS [J].

CHADI, DJ .

PHYSICAL REVIEW B, 1977, 16 (04) :1746-1747

[32] NEW NONLINEAR-OPTICAL CRYSTAL - CESIUM LITHIUM BORATE [J].

MORI, Y ;

KURODA, I ;

NAKAJIMA, S ;

SASAKI, T ;

NAKAI, S .

APPLIED PHYSICS LETTERS, 1995, 67 (13) :1818-1820

[33] ITERATIVE MINIMIZATION TECHNIQUES FOR ABINITIO TOTAL-ENERGY CALCULATIONS - MOLECULAR-DYNAMICS AND CONJUGATE GRADIENTS [J].

PAYNE, MC ;

TETER, MP ;

ALLAN, DC ;

ARIAS, TA ;

JOANNOPOULOS, JD .

REVIEWS OF MODERN PHYSICS, 1992, 64 (04) :1045-1097

[34] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[35] CSLIB6O10 - A NONCENTROSYMMETRIC POLYBORATE [J].

TU, JM ;

KESZLER, DA .

MATERIALS RESEARCH BULLETIN, 1995, 30 (02) :209-215

[36] Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals [J].

Wang, Shichao ;

Ye, Ning ;

Li, Wei ;

Zhao, Dan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (25) :8779-8786

[37] K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge [J].

Wu, Hongping ;

Pan, Shilie ;

Poeppelmeier, Kenneth R. ;

Li, Hongyi ;

Jia, Dianzeng ;

Chen, Zhaohui ;

Fan, Xiaoyun ;

Yang, Yun ;

Rondinelli, James M. ;

Luo, Haosu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (20) :7786-7790

[38] CSB3O5 - A NEW NONLINEAR-OPTICAL CRYSTAL [J].

WU, YC ;

SASAKI, T ;

NAKAI, S ;

YOKOTANI, A ;

TANG, HG ;

CHEN, CT .

APPLIED PHYSICS LETTERS, 1993, 62 (21) :2614-2615

[39] A Strong Second-Harmonic Generation Material Cd4BiO(BO3)3 Originating from 3-Chromophore Asymmetric Structures [J].

Zhang, Wei-Long ;

Cheng, Wen-Dan ;

Zhang, Hao ;

Geng, Lei ;

Lin, Chen-Sheng ;

He, Zhang-Zhen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) :1508-+

← 1 2 3 4 →