NaSr3Be3B3O9F4: A Promising Deep-Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10- Anionic Group

被引：336

作者：

Huang, Hongwei ^{[1
]}

Yao, Jiyong ^{[1
]}

Lin, Zheshuai ^{[1
]}

Wang, Xiaoyang ^{[1
]}

He, Ran ^{[1
]}

Yao, Wenjiao ^{[1
]}

Zhai, Naixia ^{[1
]}

Chen, Chuangtian ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 39期

基金：

中国国家自然科学基金;

关键词：

borates; electronic structure; nonlinear optics; solid-state structures; structure-property relationships; STRONG 2ND-HARMONIC GENERATION; UV ABSORPTION; CRYSTALS; BORATE; PSEUDOPOTENTIALS; MODEL; EDGE; RB;

D O I：

10.1002/anie.201103960

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structure matters: Owing to the structure and arrangement of the [Be 3B3O12F]10- group (see picture, left, Be blue, B olive, F green, O red), the mixed-cation fluorine beryllium borate NaSr3Be3B3O9F4 (right) exhibits a large second harmonic generation effect and a short UV absorption edge. Its crystals show no layering tendency, making it promising for applications in deep-UV nonlinear optics. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9141 / 9144

页数：4

共 39 条

[1]

Becker P, 1998, ADV MATER, V10, P979, DOI 10.1002/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO

[2]

2-N

[3]

Bera T.K., 2008, ANGEW CHEM INT EDIT, V120, P7946

[4] Soluble direct-band-gap semiconductors LiAsS2 and NaAsS2:: Large electronic structure effects from weak As•••S interactions and strong nonlinear optical response [J].

Bera, Tarun K. ;

Song, Jung-Hwan ;

Freeman, Arthur J. ;

Jang, Joon I. ;

Ketterson, John B. ;

Kanatzidis, Mercouri G. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (41) :7828-7832

[5] Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb) [J].

Bera, Tarun K. ;

Jang, Joon I. ;

Ketterson, John B. ;

Kanatzidis, Mercouri G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :75-+

[6]

Brese E., 1991, ACTA CRYSTALLOGR B, V47, P192

[7] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[8] The development of new borate-based UV nonlinear optical crystals [J].

Chen, C ;

Lin, Z ;

Wang, Z .

APPLIED PHYSICS B-LASERS AND OPTICS, 2005, 80 (01) :1-25

[9]

CHEN C, 1979, SCI SINICA, V22, P756

[10] Deep-UV nonlinear optical crystal KBe2BO3F2-discovery, growth, optical properties and applications [J].

Chen, C. T. ;

Wang, G. L. ;

Wang, X. Y. ;

Xu, Z. Y. .

APPLIED PHYSICS B-LASERS AND OPTICS, 2009, 97 (01) :9-25

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