Chemistry and structure of diterpene compounds of the kaurane series: VIII. Azomethines derived from isosteviol

被引：15

作者：

Al'fonsov, VA ^{[1
]}

Andreeva, OV ^{[1
]}

Bakaleinik, GA ^{[1
]}

Beskrovnyi, DV ^{[1
]}

Gubaidullin, AT ^{[1
]}

Kataev, VE ^{[1
]}

Kovylyaeva, GI ^{[1
]}

Konovalov, AI ^{[1
]}

Korochkina, MG ^{[1
]}

Litvinov, IA ^{[1
]}

Militsina, OI ^{[1
]}

Strobykina, IY ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

Methyl; Methanol; Ester; Methyl Ester; Oxime;

D O I：

10.1023/B:RUGC.0000007651.53262.a5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(4alpha,8beta,13beta)-13-Methyl-16-oxo-17-norkaurane-18-carboxylic acid (isosteviol) and its methyl ester were reacted with benzylamine and hydroxylamine to obtain the corresponding E-stereoisomeric 16-ketimines. Isosteviol benzylimine and oxime form individual 1: 1 H-bonded complexes with methanol and water, respectively.

引用

页码：1255 / 1260

页数：6

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