Monitoring frontal photopolymerization by electroresistance

被引：28

作者：

Cui, Yanyan ^{[1
]}

Yang, Jianwen ^{[1
]}

Zeng, Zhaohua ^{[1
]}

Zeng, Zhi ^{[1
]}

Chen, Yonglie ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Inst Polymer Sci, Guangzhou 510275, Guangdong, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 09期

基金：

中国国家自然科学基金;

关键词：

frontal photopolymerization; electrical resistance; acrylate; Rayleigh-Taylor effect;

D O I：

10.1016/j.eurpolymj.2007.06.047

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The frontal photopolymerization of acrylates was conducted in tube with TPO as bleachable photoinitiator and was identified to reach complete conversion in the formed polymer phase. The spatiotemporal temperature profiles of the frontal photopolymerization of acrylates were detected with a series of immobilized thermocouples along with the reactor. Monomer with high functionality resulted great summit temperature and was favorable for accelerating the traveling of polymerization front. It was found that the front traveling may be affected by the protruded thermocouples head. Based on the sudden increase of electrical resistance during rapid photopolymerization, an electrical measurement was setup to follow the front traveling of frontal photopolymerization. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3912 / 3922

页数：11

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