Study of brine-halite phase separation through optical constringence and molecular dynamics

被引：0

作者：

Lenart, Vinicius M. ^{[1
]}

de Lara, Lucas S. ^{[2
]}

Gomez, Sergio L. ^{[2
]}

Turchiello, Rozane F. ^{[1
]}

机构：

[1] Univ Tecnol Fed Parana, Phys Dept, Doutor Washington Subtil Chueire 330, BR-84017220 Ponta Grossa, Parana, Brazil

[2] Univ Estadual Ponta Grossa, Dept Phys, Carlos Cavalcanti 4748, BR-84030900 Ponta Grossa, Parana, Brazil

来源：

EUROPEAN PHYSICAL JOURNAL E | 2022年 / 45卷 / 07期

关键词：

REFRACTIVE-INDEX; NACL; NUCLEATION; WATER; CRYSTALS; RANGE; KCL;

D O I：

10.1140/epje/s10189-022-00214-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work presents a study of the reciprocal dispersive power, also known as constringence or Abbe number of an aqueous solution of NaCl in a wide range of concentrations. The constringence exhibited a distinct behavior in the region close to the phase transition between a phase containing exclusively brine and a phase containing brine+halite. Molecular dynamics simulations of this system indicated the existence of halite formation below the known saturation curve, which agreed with the experimental measurements, indicating a crystal growth in the unsaturated region.

引用

页数：8

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