Tris(1,10-phenanthroline)nickel(II)hexamolybdate

被引：2
作者：
Wang, WJ
Xu, L [1 ]
Gao, GG
Wei, YG
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
[2] Baicheng Teachers Coll, Dept Chem, Baicheng 137000, Peoples R China
[3] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
[4] Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Dept Chem, Beijing 100871, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805009748
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ni(C8H6N2)(3)][Mo6O19], contains centrosymmetric [Mo6O19](2-) hexamolybdate anions, which are built up from distorted MoO6 units by edge-sharing. The nickel atom in the [Ni(phen)(3)](2+) cation adopts distorted octahedral coordination with three N,N'-bidentate 1,10-phenanthroline ( phen) ligands. The crystal packing is stabilized by some weak pi-pi stacking interactions between neighboring phen ligands, and some C-H center dot center dot center dot O interactions. The Ni atom occupies a special position with twofold symmetry.
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页码：M813 / M815
页数：3
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