Polyoxometalate-Based N-Heterocyclic Carbene (NHC) Complexes for Palladium-Mediated C-C Coupling and Chloroaryl Dehalogenation Catalysis

被引：51
|
作者：
Berardi, Serena [2 ,3 ]
Carraro, Mauro [2 ,3 ]
Iglesias, Manuel [1 ]
Sartorel, Andrea [2 ,3 ]
Scorrano, Gianfranco [2 ,3 ]
Albrecht, Martin [1 ]
Bonchio, Marcella [2 ,3 ]
机构：
[1] Univ Fribourg, Dept Chem, CH-1700 Fribourg, Switzerland
[2] Univ Padua, ITM CNR, I-35131 Padua, Italy
[3] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 35期
关键词：
carbenes; homogeneous catalysis; palladium; polyoxometalates; TEMPERATURE SUZUKI-MIYAURA; ARYL CHLORIDES; HIGHLY EFFICIENT; CARBON-CARBON; NANOSTRUCTURES; WATER; OXIDATION; CHEMISTRY; LIGAND; VINYL;
D O I：
10.1002/chem.201001009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10662 / 10666
页数：5
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